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Hexaaquamagnesium(II) bis{5-[3-(1H-tetrazol-5-yl)phenyl]tetrazolide} tetrahydrate
The asymmetric unit of the title compound, [Mg(H(2)O)(6)](C(8)H(5)N(8))(2)·4H(2)O, contains one half of the centrosymmetric dication, one anion and two water molecules. The Mg(II) ion is coordinated by six water molecules in a slightly distorted octahedral geometry. In the anion, the two five-mem...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2012
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274901/ https://www.ncbi.nlm.nih.gov/pubmed/22346848 http://dx.doi.org/10.1107/S1600536812001250 |
| Sumario: | The asymmetric unit of the title compound, [Mg(H(2)O)(6)](C(8)H(5)N(8))(2)·4H(2)O, contains one half of the centrosymmetric dication, one anion and two water molecules. The Mg(II) ion is coordinated by six water molecules in a slightly distorted octahedral geometry. In the anion, the two five-membered heterocycles are twisted from the central benzene ring by 4.34 (11) and 3.20 (10)°. In the crystal, O—H⋯N, O—H⋯O and N—H⋯O hydrogen bonds generate a three-dimensional network. |
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