2-Amino­pyridinium bis­(pyridine-2,6-dicarboxyl­ato)ferrate(III)

In the title compound, (C(5)H(7)N(2))[Fe(C(7)H(3)NO(4))(2)] or [2-apyH][Fe(pydc)(2)], the asymmetric unit contains an [Fe(pydc)(2)](−) (pydc is pyridine-2,6-dicarboxyl­ate) anion and a protonated 2-amino­pyridine cation ([2-apyH](+)). The complex anion contains an Fe(III) atom within a distorted oct...

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Detalles Bibliográficos
Autores principales: Mirzaei, Masoud, Eshtiagh-Hosseini, Hossein, Mague, Joel T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274902/
https://www.ncbi.nlm.nih.gov/pubmed/22346849
http://dx.doi.org/10.1107/S1600536812001493
Descripción
Sumario:In the title compound, (C(5)H(7)N(2))[Fe(C(7)H(3)NO(4))(2)] or [2-apyH][Fe(pydc)(2)], the asymmetric unit contains an [Fe(pydc)(2)](−) (pydc is pyridine-2,6-dicarboxyl­ate) anion and a protonated 2-amino­pyridine cation ([2-apyH](+)). The complex anion contains an Fe(III) atom within a distorted octahedral FeN(2)O(4) coordination geometry. N—H⋯O and C—H⋯O hydrogen bonding, offset π–π stacking [centroid–centroid distance = 3.805 (13) Å] and C=O⋯π inter­actions [3.494 (14) Å] generate a three-dimensional network structure.

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