2-Amino­pyridinium bis­(pyridine-2,6-dicarboxyl­ato)ferrate(III)

In the title compound, (C(5)H(7)N(2))[Fe(C(7)H(3)NO(4))(2)] or [2-apyH][Fe(pydc)(2)], the asymmetric unit contains an [Fe(pydc)(2)](−) (pydc is pyridine-2,6-dicarboxyl­ate) anion and a protonated 2-amino­pyridine cation ([2-apyH](+)). The complex anion contains an Fe(III) atom within a distorted oct...

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Detalles Bibliográficos
Autores principales: Mirzaei, Masoud, Eshtiagh-Hosseini, Hossein, Mague, Joel T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274902/
https://www.ncbi.nlm.nih.gov/pubmed/22346849
http://dx.doi.org/10.1107/S1600536812001493
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author Mirzaei, Masoud
Eshtiagh-Hosseini, Hossein
Mague, Joel T.
author_facet Mirzaei, Masoud
Eshtiagh-Hosseini, Hossein
Mague, Joel T.
author_sort Mirzaei, Masoud
collection PubMed
description In the title compound, (C(5)H(7)N(2))[Fe(C(7)H(3)NO(4))(2)] or [2-apyH][Fe(pydc)(2)], the asymmetric unit contains an [Fe(pydc)(2)](−) (pydc is pyridine-2,6-dicarboxyl­ate) anion and a protonated 2-amino­pyridine cation ([2-apyH](+)). The complex anion contains an Fe(III) atom within a distorted octahedral FeN(2)O(4) coordination geometry. N—H⋯O and C—H⋯O hydrogen bonding, offset π–π stacking [centroid–centroid distance = 3.805 (13) Å] and C=O⋯π inter­actions [3.494 (14) Å] generate a three-dimensional network structure.
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spelling pubmed-32749022012-02-15 2-Amino­pyridinium bis­(pyridine-2,6-dicarboxyl­ato)ferrate(III) Mirzaei, Masoud Eshtiagh-Hosseini, Hossein Mague, Joel T. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, (C(5)H(7)N(2))[Fe(C(7)H(3)NO(4))(2)] or [2-apyH][Fe(pydc)(2)], the asymmetric unit contains an [Fe(pydc)(2)](−) (pydc is pyridine-2,6-dicarboxyl­ate) anion and a protonated 2-amino­pyridine cation ([2-apyH](+)). The complex anion contains an Fe(III) atom within a distorted octahedral FeN(2)O(4) coordination geometry. N—H⋯O and C—H⋯O hydrogen bonding, offset π–π stacking [centroid–centroid distance = 3.805 (13) Å] and C=O⋯π inter­actions [3.494 (14) Å] generate a three-dimensional network structure. International Union of Crystallography 2012-01-21 /pmc/articles/PMC3274902/ /pubmed/22346849 http://dx.doi.org/10.1107/S1600536812001493 Text en © Mirzaei et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Mirzaei, Masoud
Eshtiagh-Hosseini, Hossein
Mague, Joel T.
2-Amino­pyridinium bis­(pyridine-2,6-dicarboxyl­ato)ferrate(III)
title 2-Amino­pyridinium bis­(pyridine-2,6-dicarboxyl­ato)ferrate(III)
title_full 2-Amino­pyridinium bis­(pyridine-2,6-dicarboxyl­ato)ferrate(III)
title_fullStr 2-Amino­pyridinium bis­(pyridine-2,6-dicarboxyl­ato)ferrate(III)
title_full_unstemmed 2-Amino­pyridinium bis­(pyridine-2,6-dicarboxyl­ato)ferrate(III)
title_short 2-Amino­pyridinium bis­(pyridine-2,6-dicarboxyl­ato)ferrate(III)
title_sort 2-amino­pyridinium bis­(pyridine-2,6-dicarboxyl­ato)ferrate(iii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274902/
https://www.ncbi.nlm.nih.gov/pubmed/22346849
http://dx.doi.org/10.1107/S1600536812001493
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AT eshtiaghhosseinihossein 2aminopyridiniumbispyridine26dicarboxylatoferrateiii
AT maguejoelt 2aminopyridiniumbispyridine26dicarboxylatoferrateiii

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