Poly[piperazine-1,4-diium [μ(4)-chlorido-μ(3)-chlorido-tri-μ(2)-chlorido-chloridodicadmate(II)] monohydrate]

In the title compound, {(C(5)H(14)N(2))[Cd(2)Cl(6)]·H(2)O}(n), the asymmetric unit contains one piperazinediium cation, one [Cd(2)Cl(6)](2−) anion and a water mol­ecule. The coordination geometries of the two Cd(2+) cations are distorted octa­hedral. Adjacent Cd(II) atoms are inter­connected alterna...

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Autores principales: Adib, Marwa, El Glaoui, Meher, Pereira da Silva, Pedro Sidonio, Ramos Silva, Manuela, Ben Nasr, Cherif
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274903/
https://www.ncbi.nlm.nih.gov/pubmed/22346850
http://dx.doi.org/10.1107/S1600536812001626
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author Adib, Marwa
El Glaoui, Meher
Pereira da Silva, Pedro Sidonio
Ramos Silva, Manuela
Ben Nasr, Cherif
author_facet Adib, Marwa
El Glaoui, Meher
Pereira da Silva, Pedro Sidonio
Ramos Silva, Manuela
Ben Nasr, Cherif
author_sort Adib, Marwa
collection PubMed
description In the title compound, {(C(5)H(14)N(2))[Cd(2)Cl(6)]·H(2)O}(n), the asymmetric unit contains one piperazinediium cation, one [Cd(2)Cl(6)](2−) anion and a water mol­ecule. The coordination geometries of the two Cd(2+) cations are distorted octa­hedral. Adjacent Cd(II) atoms are inter­connected alternately by paired chloride bridges, generating polymeric chains parallel to [010]. Neighbouring chains are connected by O—H⋯Cl hydrogen bonds involving the water mol­ecules, forming layers at z = n/2. The crystal packing is further stabilized by inter­molecular N—H⋯Cl and N—H⋯O hydrogen bonds, one of which is bifurcated.
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spelling pubmed-32749032012-02-15 Poly[piperazine-1,4-diium [μ(4)-chlorido-μ(3)-chlorido-tri-μ(2)-chlorido-chloridodicadmate(II)] monohydrate] Adib, Marwa El Glaoui, Meher Pereira da Silva, Pedro Sidonio Ramos Silva, Manuela Ben Nasr, Cherif Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, {(C(5)H(14)N(2))[Cd(2)Cl(6)]·H(2)O}(n), the asymmetric unit contains one piperazinediium cation, one [Cd(2)Cl(6)](2−) anion and a water mol­ecule. The coordination geometries of the two Cd(2+) cations are distorted octa­hedral. Adjacent Cd(II) atoms are inter­connected alternately by paired chloride bridges, generating polymeric chains parallel to [010]. Neighbouring chains are connected by O—H⋯Cl hydrogen bonds involving the water mol­ecules, forming layers at z = n/2. The crystal packing is further stabilized by inter­molecular N—H⋯Cl and N—H⋯O hydrogen bonds, one of which is bifurcated. International Union of Crystallography 2012-01-21 /pmc/articles/PMC3274903/ /pubmed/22346850 http://dx.doi.org/10.1107/S1600536812001626 Text en © Adib et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Adib, Marwa
El Glaoui, Meher
Pereira da Silva, Pedro Sidonio
Ramos Silva, Manuela
Ben Nasr, Cherif
Poly[piperazine-1,4-diium [μ(4)-chlorido-μ(3)-chlorido-tri-μ(2)-chlorido-chloridodicadmate(II)] monohydrate]
title Poly[piperazine-1,4-diium [μ(4)-chlorido-μ(3)-chlorido-tri-μ(2)-chlorido-chloridodicadmate(II)] monohydrate]
title_full Poly[piperazine-1,4-diium [μ(4)-chlorido-μ(3)-chlorido-tri-μ(2)-chlorido-chloridodicadmate(II)] monohydrate]
title_fullStr Poly[piperazine-1,4-diium [μ(4)-chlorido-μ(3)-chlorido-tri-μ(2)-chlorido-chloridodicadmate(II)] monohydrate]
title_full_unstemmed Poly[piperazine-1,4-diium [μ(4)-chlorido-μ(3)-chlorido-tri-μ(2)-chlorido-chloridodicadmate(II)] monohydrate]
title_short Poly[piperazine-1,4-diium [μ(4)-chlorido-μ(3)-chlorido-tri-μ(2)-chlorido-chloridodicadmate(II)] monohydrate]
title_sort poly[piperazine-1,4-diium [μ(4)-chlorido-μ(3)-chlorido-tri-μ(2)-chlorido-chloridodicadmate(ii)] monohydrate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274903/
https://www.ncbi.nlm.nih.gov/pubmed/22346850
http://dx.doi.org/10.1107/S1600536812001626
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