Cargando…

Bis(2-amino-1,3-benzothia­zole-κN (3))dichloridozinc(II) ethanol hemisolvate

In the title compound, [ZnCl(2)(C(7)H(6)N(2)S)(2)]·0.5CH(3)CH(2)OH, the Zn(II) atom is coordinated by two N atoms of two 2-amino­benzothia­zole ligands and two Cl atoms within a distorted tetra­hedral geometry. The dihedral angle between the N/Zn/N and Cl/Zn/Cl planes is 86.22 (7)°. The benzothia­zo...

Descripción completa

Detalles Bibliográficos
Autores principales: Kim, Young-Inn, Kang, Sung Kwon
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274905/
https://www.ncbi.nlm.nih.gov/pubmed/22346852
http://dx.doi.org/10.1107/S1600536812001560
_version_ 1782223132297265152
author Kim, Young-Inn
Kang, Sung Kwon
author_facet Kim, Young-Inn
Kang, Sung Kwon
author_sort Kim, Young-Inn
collection PubMed
description In the title compound, [ZnCl(2)(C(7)H(6)N(2)S)(2)]·0.5CH(3)CH(2)OH, the Zn(II) atom is coordinated by two N atoms of two 2-amino­benzothia­zole ligands and two Cl atoms within a distorted tetra­hedral geometry. The dihedral angle between the N/Zn/N and Cl/Zn/Cl planes is 86.22 (7)°. The benzothia­zole mol­ecules are almost perpendicular to each other, forming a dihedral angle of 80.20 (8)°. The mol­ecular structure is stabilized by intra­molecular N—H⋯Cl hydrogen bonds. In the crystal, inter­molecular N—H⋯Cl hydrogen bonds link the mol­ecules into a three-dimensional network. The SQUEEZE procedure in PLATON [Spek (2009 ▶). Acta Cryst. D65, 148–155] was used to model a disordered ethanol solvent mol­ecule; the calculated unit-cell data allow for the presence of half of this mol­ecule in the asymmetric unit.
format Online
Article
Text
id pubmed-3274905
institution National Center for Biotechnology Information
language English
publishDate 2012
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-32749052012-02-15 Bis(2-amino-1,3-benzothia­zole-κN (3))dichloridozinc(II) ethanol hemisolvate Kim, Young-Inn Kang, Sung Kwon Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [ZnCl(2)(C(7)H(6)N(2)S)(2)]·0.5CH(3)CH(2)OH, the Zn(II) atom is coordinated by two N atoms of two 2-amino­benzothia­zole ligands and two Cl atoms within a distorted tetra­hedral geometry. The dihedral angle between the N/Zn/N and Cl/Zn/Cl planes is 86.22 (7)°. The benzothia­zole mol­ecules are almost perpendicular to each other, forming a dihedral angle of 80.20 (8)°. The mol­ecular structure is stabilized by intra­molecular N—H⋯Cl hydrogen bonds. In the crystal, inter­molecular N—H⋯Cl hydrogen bonds link the mol­ecules into a three-dimensional network. The SQUEEZE procedure in PLATON [Spek (2009 ▶). Acta Cryst. D65, 148–155] was used to model a disordered ethanol solvent mol­ecule; the calculated unit-cell data allow for the presence of half of this mol­ecule in the asymmetric unit. International Union of Crystallography 2012-01-21 /pmc/articles/PMC3274905/ /pubmed/22346852 http://dx.doi.org/10.1107/S1600536812001560 Text en © Kim and Kang 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Kim, Young-Inn
Kang, Sung Kwon
Bis(2-amino-1,3-benzothia­zole-κN (3))dichloridozinc(II) ethanol hemisolvate
title Bis(2-amino-1,3-benzothia­zole-κN (3))dichloridozinc(II) ethanol hemisolvate
title_full Bis(2-amino-1,3-benzothia­zole-κN (3))dichloridozinc(II) ethanol hemisolvate
title_fullStr Bis(2-amino-1,3-benzothia­zole-κN (3))dichloridozinc(II) ethanol hemisolvate
title_full_unstemmed Bis(2-amino-1,3-benzothia­zole-κN (3))dichloridozinc(II) ethanol hemisolvate
title_short Bis(2-amino-1,3-benzothia­zole-κN (3))dichloridozinc(II) ethanol hemisolvate
title_sort bis(2-amino-1,3-benzothia­zole-κn (3))dichloridozinc(ii) ethanol hemisolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274905/
https://www.ncbi.nlm.nih.gov/pubmed/22346852
http://dx.doi.org/10.1107/S1600536812001560
work_keys_str_mv AT kimyounginn bis2amino13benzothiazolekn3dichloridozinciiethanolhemisolvate
AT kangsungkwon bis2amino13benzothiazolekn3dichloridozinciiethanolhemisolvate