Cargando…
Bis(2-amino-1,3-benzothiazole-κN (3))dichloridozinc(II) ethanol hemisolvate
In the title compound, [ZnCl(2)(C(7)H(6)N(2)S)(2)]·0.5CH(3)CH(2)OH, the Zn(II) atom is coordinated by two N atoms of two 2-aminobenzothiazole ligands and two Cl atoms within a distorted tetrahedral geometry. The dihedral angle between the N/Zn/N and Cl/Zn/Cl planes is 86.22 (7)°. The benzothiazo...
Autores principales: | , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274905/ https://www.ncbi.nlm.nih.gov/pubmed/22346852 http://dx.doi.org/10.1107/S1600536812001560 |
_version_ | 1782223132297265152 |
---|---|
author | Kim, Young-Inn Kang, Sung Kwon |
author_facet | Kim, Young-Inn Kang, Sung Kwon |
author_sort | Kim, Young-Inn |
collection | PubMed |
description | In the title compound, [ZnCl(2)(C(7)H(6)N(2)S)(2)]·0.5CH(3)CH(2)OH, the Zn(II) atom is coordinated by two N atoms of two 2-aminobenzothiazole ligands and two Cl atoms within a distorted tetrahedral geometry. The dihedral angle between the N/Zn/N and Cl/Zn/Cl planes is 86.22 (7)°. The benzothiazole molecules are almost perpendicular to each other, forming a dihedral angle of 80.20 (8)°. The molecular structure is stabilized by intramolecular N—H⋯Cl hydrogen bonds. In the crystal, intermolecular N—H⋯Cl hydrogen bonds link the molecules into a three-dimensional network. The SQUEEZE procedure in PLATON [Spek (2009 ▶). Acta Cryst. D65, 148–155] was used to model a disordered ethanol solvent molecule; the calculated unit-cell data allow for the presence of half of this molecule in the asymmetric unit. |
format | Online Article Text |
id | pubmed-3274905 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32749052012-02-15 Bis(2-amino-1,3-benzothiazole-κN (3))dichloridozinc(II) ethanol hemisolvate Kim, Young-Inn Kang, Sung Kwon Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [ZnCl(2)(C(7)H(6)N(2)S)(2)]·0.5CH(3)CH(2)OH, the Zn(II) atom is coordinated by two N atoms of two 2-aminobenzothiazole ligands and two Cl atoms within a distorted tetrahedral geometry. The dihedral angle between the N/Zn/N and Cl/Zn/Cl planes is 86.22 (7)°. The benzothiazole molecules are almost perpendicular to each other, forming a dihedral angle of 80.20 (8)°. The molecular structure is stabilized by intramolecular N—H⋯Cl hydrogen bonds. In the crystal, intermolecular N—H⋯Cl hydrogen bonds link the molecules into a three-dimensional network. The SQUEEZE procedure in PLATON [Spek (2009 ▶). Acta Cryst. D65, 148–155] was used to model a disordered ethanol solvent molecule; the calculated unit-cell data allow for the presence of half of this molecule in the asymmetric unit. International Union of Crystallography 2012-01-21 /pmc/articles/PMC3274905/ /pubmed/22346852 http://dx.doi.org/10.1107/S1600536812001560 Text en © Kim and Kang 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Kim, Young-Inn Kang, Sung Kwon Bis(2-amino-1,3-benzothiazole-κN (3))dichloridozinc(II) ethanol hemisolvate |
title | Bis(2-amino-1,3-benzothiazole-κN
(3))dichloridozinc(II) ethanol hemisolvate |
title_full | Bis(2-amino-1,3-benzothiazole-κN
(3))dichloridozinc(II) ethanol hemisolvate |
title_fullStr | Bis(2-amino-1,3-benzothiazole-κN
(3))dichloridozinc(II) ethanol hemisolvate |
title_full_unstemmed | Bis(2-amino-1,3-benzothiazole-κN
(3))dichloridozinc(II) ethanol hemisolvate |
title_short | Bis(2-amino-1,3-benzothiazole-κN
(3))dichloridozinc(II) ethanol hemisolvate |
title_sort | bis(2-amino-1,3-benzothiazole-κn
(3))dichloridozinc(ii) ethanol hemisolvate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274905/ https://www.ncbi.nlm.nih.gov/pubmed/22346852 http://dx.doi.org/10.1107/S1600536812001560 |
work_keys_str_mv | AT kimyounginn bis2amino13benzothiazolekn3dichloridozinciiethanolhemisolvate AT kangsungkwon bis2amino13benzothiazolekn3dichloridozinciiethanolhemisolvate |