All­yl(ferrocenylmeth­yl)dimethyl­ammonium perchlorate

The asymmetric unit of the title complex, [Fe(C(5)H(5))(C(11)H(17)N)]ClO(4), contains two independent all­yl(ferro­cenyl­meth­yl)dimethyl­ammonium cations and two ClO(4) (−) anions. The anions are disordered each over two sets of sites, with an occupancy ratio of 0.617 (6):0.383 (6). The distances f...

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Detalles Bibliográficos
Autor principal: Wang, Ying-Chun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274906/
https://www.ncbi.nlm.nih.gov/pubmed/22346853
http://dx.doi.org/10.1107/S1600536812001766
Descripción
Sumario:The asymmetric unit of the title complex, [Fe(C(5)H(5))(C(11)H(17)N)]ClO(4), contains two independent all­yl(ferro­cenyl­meth­yl)dimethyl­ammonium cations and two ClO(4) (−) anions. The anions are disordered each over two sets of sites, with an occupancy ratio of 0.617 (6):0.383 (6). The distances from the Fe atoms to the centroids of the unsubstituted and substituted cyclo­penta­dienyl (Cp) rings are 1.645 (1)/1.657 (1) and 1.644 (1)/1.647 (1) Å. The dihedral angles between the two Cp rings are 2.49 (3) and 1.45 (4)° in the two ferrocenyl groups of the cations.

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