All­yl(ferrocenylmeth­yl)dimethyl­ammonium perchlorate

The asymmetric unit of the title complex, [Fe(C(5)H(5))(C(11)H(17)N)]ClO(4), contains two independent all­yl(ferro­cenyl­meth­yl)dimethyl­ammonium cations and two ClO(4) (−) anions. The anions are disordered each over two sets of sites, with an occupancy ratio of 0.617 (6):0.383 (6). The distances f...

Descripción completa

Detalles Bibliográficos
Autor principal: Wang, Ying-Chun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274906/
https://www.ncbi.nlm.nih.gov/pubmed/22346853
http://dx.doi.org/10.1107/S1600536812001766
_version_ 1782223132526903296
author Wang, Ying-Chun
author_facet Wang, Ying-Chun
author_sort Wang, Ying-Chun
collection PubMed
description The asymmetric unit of the title complex, [Fe(C(5)H(5))(C(11)H(17)N)]ClO(4), contains two independent all­yl(ferro­cenyl­meth­yl)dimethyl­ammonium cations and two ClO(4) (−) anions. The anions are disordered each over two sets of sites, with an occupancy ratio of 0.617 (6):0.383 (6). The distances from the Fe atoms to the centroids of the unsubstituted and substituted cyclo­penta­dienyl (Cp) rings are 1.645 (1)/1.657 (1) and 1.644 (1)/1.647 (1) Å. The dihedral angles between the two Cp rings are 2.49 (3) and 1.45 (4)° in the two ferrocenyl groups of the cations.
format Online
Article
Text
id pubmed-3274906
institution National Center for Biotechnology Information
language English
publishDate 2012
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-32749062012-02-15 All­yl(ferrocenylmeth­yl)dimethyl­ammonium perchlorate Wang, Ying-Chun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title complex, [Fe(C(5)H(5))(C(11)H(17)N)]ClO(4), contains two independent all­yl(ferro­cenyl­meth­yl)dimethyl­ammonium cations and two ClO(4) (−) anions. The anions are disordered each over two sets of sites, with an occupancy ratio of 0.617 (6):0.383 (6). The distances from the Fe atoms to the centroids of the unsubstituted and substituted cyclo­penta­dienyl (Cp) rings are 1.645 (1)/1.657 (1) and 1.644 (1)/1.647 (1) Å. The dihedral angles between the two Cp rings are 2.49 (3) and 1.45 (4)° in the two ferrocenyl groups of the cations. International Union of Crystallography 2012-01-21 /pmc/articles/PMC3274906/ /pubmed/22346853 http://dx.doi.org/10.1107/S1600536812001766 Text en © Ying-Chun Wang 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wang, Ying-Chun
All­yl(ferrocenylmeth­yl)dimethyl­ammonium perchlorate
title All­yl(ferrocenylmeth­yl)dimethyl­ammonium perchlorate
title_full All­yl(ferrocenylmeth­yl)dimethyl­ammonium perchlorate
title_fullStr All­yl(ferrocenylmeth­yl)dimethyl­ammonium perchlorate
title_full_unstemmed All­yl(ferrocenylmeth­yl)dimethyl­ammonium perchlorate
title_short All­yl(ferrocenylmeth­yl)dimethyl­ammonium perchlorate
title_sort all­yl(ferrocenylmeth­yl)dimethyl­ammonium perchlorate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274906/
https://www.ncbi.nlm.nih.gov/pubmed/22346853
http://dx.doi.org/10.1107/S1600536812001766
work_keys_str_mv AT wangyingchun allylferrocenylmethyldimethylammoniumperchlorate

Ejemplares similares