catena-Poly[4-methyl­morpholin-4-ium [[dichloridobismuth(III)]-di-μ-chlorido]]

The asymmetric unit of the title complex, {(C(5)H(12)NO)[BiCl(4)]}(n), contains two bridging and two cis non-bridging chloride ligands coordinated to a central Bi(III) atom, and one 4-methyl­morpholin-4-ium cation. The Bi(III) atoms are linked by the bridging chloride ligands into linear chains para...

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Detalles Bibliográficos
Autor principal: Wang, Ying-Chun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274907/
https://www.ncbi.nlm.nih.gov/pubmed/22346854
http://dx.doi.org/10.1107/S1600536812001717
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author Wang, Ying-Chun
author_facet Wang, Ying-Chun
author_sort Wang, Ying-Chun
collection PubMed
description The asymmetric unit of the title complex, {(C(5)H(12)NO)[BiCl(4)]}(n), contains two bridging and two cis non-bridging chloride ligands coordinated to a central Bi(III) atom, and one 4-methyl­morpholin-4-ium cation. The Bi(III) atoms are linked by the bridging chloride ligands into linear chains parallel to the c axis. The chloride ions create a pseudo-octa­hedral geometry about each Bi(III) atom. Bifurcated N—H⋯Cl hydrogen bonds link the cations to the anionic chains.
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spelling pubmed-32749072012-02-15 catena-Poly[4-methyl­morpholin-4-ium [[dichloridobismuth(III)]-di-μ-chlorido]] Wang, Ying-Chun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title complex, {(C(5)H(12)NO)[BiCl(4)]}(n), contains two bridging and two cis non-bridging chloride ligands coordinated to a central Bi(III) atom, and one 4-methyl­morpholin-4-ium cation. The Bi(III) atoms are linked by the bridging chloride ligands into linear chains parallel to the c axis. The chloride ions create a pseudo-octa­hedral geometry about each Bi(III) atom. Bifurcated N—H⋯Cl hydrogen bonds link the cations to the anionic chains. International Union of Crystallography 2012-01-21 /pmc/articles/PMC3274907/ /pubmed/22346854 http://dx.doi.org/10.1107/S1600536812001717 Text en © Ying-Chun Wang 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wang, Ying-Chun
catena-Poly[4-methyl­morpholin-4-ium [[dichloridobismuth(III)]-di-μ-chlorido]]
title catena-Poly[4-methyl­morpholin-4-ium [[dichloridobismuth(III)]-di-μ-chlorido]]
title_full catena-Poly[4-methyl­morpholin-4-ium [[dichloridobismuth(III)]-di-μ-chlorido]]
title_fullStr catena-Poly[4-methyl­morpholin-4-ium [[dichloridobismuth(III)]-di-μ-chlorido]]
title_full_unstemmed catena-Poly[4-methyl­morpholin-4-ium [[dichloridobismuth(III)]-di-μ-chlorido]]
title_short catena-Poly[4-methyl­morpholin-4-ium [[dichloridobismuth(III)]-di-μ-chlorido]]
title_sort catena-poly[4-methyl­morpholin-4-ium [[dichloridobismuth(iii)]-di-μ-chlorido]]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274907/
https://www.ncbi.nlm.nih.gov/pubmed/22346854
http://dx.doi.org/10.1107/S1600536812001717
work_keys_str_mv AT wangyingchun catenapoly4methylmorpholin4iumdichloridobismuthiiidimchlorido

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