{4,4′,6,6′-Tetra­chloro-2,2′-[2,2-dimethyl­propane-1,3-diylbis(nitrilo­methanylyl­idene)]}copper(II)

In the title Schiff base complex, [Cu(C(19)H(16)Cl(4)N(2)O(2))], the geometry around the Cu(II) atom is distorted square-planar defined by the N(2)O(2) donor atoms of the coordinated ligand. The dihedral angle between the substituted benzene rings is 29.95 (16)°. In the crystal, mol­ecules are linke...

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Autores principales: Kargar, Hadi, Kia, Reza, Abbasian, Saeideh, Tahir, Muhammad Nawaz
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274908/
https://www.ncbi.nlm.nih.gov/pubmed/22346855
http://dx.doi.org/10.1107/S160053681200195X
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author Kargar, Hadi
Kia, Reza
Abbasian, Saeideh
Tahir, Muhammad Nawaz
author_facet Kargar, Hadi
Kia, Reza
Abbasian, Saeideh
Tahir, Muhammad Nawaz
author_sort Kargar, Hadi
collection PubMed
description In the title Schiff base complex, [Cu(C(19)H(16)Cl(4)N(2)O(2))], the geometry around the Cu(II) atom is distorted square-planar defined by the N(2)O(2) donor atoms of the coordinated ligand. The dihedral angle between the substituted benzene rings is 29.95 (16)°. In the crystal, mol­ecules are linked along the b axis, forming individual dimers through C—H⋯O inter­actions. The crystal structure is further stabilized by inter­molecular π–π inter­actions [centroid–centroid distance = 3.6131 (17) Å].
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spelling pubmed-32749082012-02-15 {4,4′,6,6′-Tetra­chloro-2,2′-[2,2-dimethyl­propane-1,3-diylbis(nitrilo­methanylyl­idene)]}copper(II) Kargar, Hadi Kia, Reza Abbasian, Saeideh Tahir, Muhammad Nawaz Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title Schiff base complex, [Cu(C(19)H(16)Cl(4)N(2)O(2))], the geometry around the Cu(II) atom is distorted square-planar defined by the N(2)O(2) donor atoms of the coordinated ligand. The dihedral angle between the substituted benzene rings is 29.95 (16)°. In the crystal, mol­ecules are linked along the b axis, forming individual dimers through C—H⋯O inter­actions. The crystal structure is further stabilized by inter­molecular π–π inter­actions [centroid–centroid distance = 3.6131 (17) Å]. International Union of Crystallography 2012-01-21 /pmc/articles/PMC3274908/ /pubmed/22346855 http://dx.doi.org/10.1107/S160053681200195X Text en © Kargar et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Kargar, Hadi
Kia, Reza
Abbasian, Saeideh
Tahir, Muhammad Nawaz
{4,4′,6,6′-Tetra­chloro-2,2′-[2,2-dimethyl­propane-1,3-diylbis(nitrilo­methanylyl­idene)]}copper(II)
title {4,4′,6,6′-Tetra­chloro-2,2′-[2,2-dimethyl­propane-1,3-diylbis(nitrilo­methanylyl­idene)]}copper(II)
title_full {4,4′,6,6′-Tetra­chloro-2,2′-[2,2-dimethyl­propane-1,3-diylbis(nitrilo­methanylyl­idene)]}copper(II)
title_fullStr {4,4′,6,6′-Tetra­chloro-2,2′-[2,2-dimethyl­propane-1,3-diylbis(nitrilo­methanylyl­idene)]}copper(II)
title_full_unstemmed {4,4′,6,6′-Tetra­chloro-2,2′-[2,2-dimethyl­propane-1,3-diylbis(nitrilo­methanylyl­idene)]}copper(II)
title_short {4,4′,6,6′-Tetra­chloro-2,2′-[2,2-dimethyl­propane-1,3-diylbis(nitrilo­methanylyl­idene)]}copper(II)
title_sort {4,4′,6,6′-tetra­chloro-2,2′-[2,2-dimethyl­propane-1,3-diylbis(nitrilo­methanylyl­idene)]}copper(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274908/
https://www.ncbi.nlm.nih.gov/pubmed/22346855
http://dx.doi.org/10.1107/S160053681200195X
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