Bis{N-ethyl-2-[3-(hy­droxy­imino-κN)butan-2-yl­idene]hydrazinecarbothio­amide-κ(2) N (2),S}nickel(II) dichloride

In the title complex, [Ni(C(7)H(14)N(4)OS)(2)]Cl(2), the Ni(II) ion is six-coordinated in a distorted octa­hedral geometry by four N atoms from the two imine and two oxime groups, and two S atoms from the thione groups. Two chloride ions complete the asymmetric unit. In the crystal, mol­ecules are l...

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Detalles Bibliográficos
Autores principales: Abduelftah, Halema Shaban, Ali, Amna Qasem, Eltayeb, Naser Eltaher, Teoh, Siang Guan, Fun, Hoong-Kun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274909/
https://www.ncbi.nlm.nih.gov/pubmed/22346856
http://dx.doi.org/10.1107/S1600536811055383
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author Abduelftah, Halema Shaban
Ali, Amna Qasem
Eltayeb, Naser Eltaher
Teoh, Siang Guan
Fun, Hoong-Kun
author_facet Abduelftah, Halema Shaban
Ali, Amna Qasem
Eltayeb, Naser Eltaher
Teoh, Siang Guan
Fun, Hoong-Kun
author_sort Abduelftah, Halema Shaban
collection PubMed
description In the title complex, [Ni(C(7)H(14)N(4)OS)(2)]Cl(2), the Ni(II) ion is six-coordinated in a distorted octa­hedral geometry by four N atoms from the two imine and two oxime groups, and two S atoms from the thione groups. Two chloride ions complete the asymmetric unit. In the crystal, mol­ecules are linked through N—H⋯Cl and O—H⋯Cl hydrogen bonds into an infinite chain propagating along [101].
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spelling pubmed-32749092012-02-15 Bis{N-ethyl-2-[3-(hy­droxy­imino-κN)butan-2-yl­idene]hydrazinecarbothio­amide-κ(2) N (2),S}nickel(II) dichloride Abduelftah, Halema Shaban Ali, Amna Qasem Eltayeb, Naser Eltaher Teoh, Siang Guan Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Ni(C(7)H(14)N(4)OS)(2)]Cl(2), the Ni(II) ion is six-coordinated in a distorted octa­hedral geometry by four N atoms from the two imine and two oxime groups, and two S atoms from the thione groups. Two chloride ions complete the asymmetric unit. In the crystal, mol­ecules are linked through N—H⋯Cl and O—H⋯Cl hydrogen bonds into an infinite chain propagating along [101]. International Union of Crystallography 2012-01-21 /pmc/articles/PMC3274909/ /pubmed/22346856 http://dx.doi.org/10.1107/S1600536811055383 Text en © Abduelftah et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Abduelftah, Halema Shaban
Ali, Amna Qasem
Eltayeb, Naser Eltaher
Teoh, Siang Guan
Fun, Hoong-Kun
Bis{N-ethyl-2-[3-(hy­droxy­imino-κN)butan-2-yl­idene]hydrazinecarbothio­amide-κ(2) N (2),S}nickel(II) dichloride
title Bis{N-ethyl-2-[3-(hy­droxy­imino-κN)butan-2-yl­idene]hydrazinecarbothio­amide-κ(2) N (2),S}nickel(II) dichloride
title_full Bis{N-ethyl-2-[3-(hy­droxy­imino-κN)butan-2-yl­idene]hydrazinecarbothio­amide-κ(2) N (2),S}nickel(II) dichloride
title_fullStr Bis{N-ethyl-2-[3-(hy­droxy­imino-κN)butan-2-yl­idene]hydrazinecarbothio­amide-κ(2) N (2),S}nickel(II) dichloride
title_full_unstemmed Bis{N-ethyl-2-[3-(hy­droxy­imino-κN)butan-2-yl­idene]hydrazinecarbothio­amide-κ(2) N (2),S}nickel(II) dichloride
title_short Bis{N-ethyl-2-[3-(hy­droxy­imino-κN)butan-2-yl­idene]hydrazinecarbothio­amide-κ(2) N (2),S}nickel(II) dichloride
title_sort bis{n-ethyl-2-[3-(hy­droxy­imino-κn)butan-2-yl­idene]hydrazinecarbothio­amide-κ(2) n (2),s}nickel(ii) dichloride
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274909/
https://www.ncbi.nlm.nih.gov/pubmed/22346856
http://dx.doi.org/10.1107/S1600536811055383
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