Cargando…
(Nitrato-κ(2) O,O′)bis(tryptanthrin-κN)silver(I)
In the crystal structure of the title compound, [Ag(NO(3))(C(15)H(8)N(2)O(2))(2)], tryptanthrin (indolo[2,1-b]quinazoline-6,12-dione) and silver nitrate form a 2:1 complex. The silver ion is surrounded by two tryptanthrin ligands, each coordinating through the N atoms, with Ag—N bond lengths of 2.24...
Autores principales: | , , , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274910/ https://www.ncbi.nlm.nih.gov/pubmed/22346857 http://dx.doi.org/10.1107/S1600536812001821 |
_version_ | 1782223133454893056 |
---|---|
author | Wu, Jie Huang, Chao Li, Guo-Qiang Tian, Hai-Yan Jiang, Ren-Wang |
author_facet | Wu, Jie Huang, Chao Li, Guo-Qiang Tian, Hai-Yan Jiang, Ren-Wang |
author_sort | Wu, Jie |
collection | PubMed |
description | In the crystal structure of the title compound, [Ag(NO(3))(C(15)H(8)N(2)O(2))(2)], tryptanthrin (indolo[2,1-b]quinazoline-6,12-dione) and silver nitrate form a 2:1 complex. The silver ion is surrounded by two tryptanthrin ligands, each coordinating through the N atoms, with Ag—N bond lengths of 2.247 (3) and 2.264 (3) Å, and an anionic nitrate ligand coordinating through two O atoms, with Ag—O bond lengths of 2.499 (3) and 2.591 (3) Å. The N—Ag—N plane and the O—Ag—O plane are roughly perpendicular, making a dihedral angle of 81.6 (2)°. In the crystal, C—H⋯O interactions between aromatic H atoms and keto and nitrate O atoms as well as π–π interactions [centroid-centroid distance = 3.706 (4) Å] give rise to a three-dimensional network. |
format | Online Article Text |
id | pubmed-3274910 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32749102012-02-15 (Nitrato-κ(2) O,O′)bis(tryptanthrin-κN)silver(I) Wu, Jie Huang, Chao Li, Guo-Qiang Tian, Hai-Yan Jiang, Ren-Wang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the crystal structure of the title compound, [Ag(NO(3))(C(15)H(8)N(2)O(2))(2)], tryptanthrin (indolo[2,1-b]quinazoline-6,12-dione) and silver nitrate form a 2:1 complex. The silver ion is surrounded by two tryptanthrin ligands, each coordinating through the N atoms, with Ag—N bond lengths of 2.247 (3) and 2.264 (3) Å, and an anionic nitrate ligand coordinating through two O atoms, with Ag—O bond lengths of 2.499 (3) and 2.591 (3) Å. The N—Ag—N plane and the O—Ag—O plane are roughly perpendicular, making a dihedral angle of 81.6 (2)°. In the crystal, C—H⋯O interactions between aromatic H atoms and keto and nitrate O atoms as well as π–π interactions [centroid-centroid distance = 3.706 (4) Å] give rise to a three-dimensional network. International Union of Crystallography 2012-01-21 /pmc/articles/PMC3274910/ /pubmed/22346857 http://dx.doi.org/10.1107/S1600536812001821 Text en © Wu et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Wu, Jie Huang, Chao Li, Guo-Qiang Tian, Hai-Yan Jiang, Ren-Wang (Nitrato-κ(2) O,O′)bis(tryptanthrin-κN)silver(I) |
title | (Nitrato-κ(2)
O,O′)bis(tryptanthrin-κN)silver(I) |
title_full | (Nitrato-κ(2)
O,O′)bis(tryptanthrin-κN)silver(I) |
title_fullStr | (Nitrato-κ(2)
O,O′)bis(tryptanthrin-κN)silver(I) |
title_full_unstemmed | (Nitrato-κ(2)
O,O′)bis(tryptanthrin-κN)silver(I) |
title_short | (Nitrato-κ(2)
O,O′)bis(tryptanthrin-κN)silver(I) |
title_sort | (nitrato-κ(2)
o,o′)bis(tryptanthrin-κn)silver(i) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274910/ https://www.ncbi.nlm.nih.gov/pubmed/22346857 http://dx.doi.org/10.1107/S1600536812001821 |
work_keys_str_mv | AT wujie nitratok2oobistryptanthrinknsilveri AT huangchao nitratok2oobistryptanthrinknsilveri AT liguoqiang nitratok2oobistryptanthrinknsilveri AT tianhaiyan nitratok2oobistryptanthrinknsilveri AT jiangrenwang nitratok2oobistryptanthrinknsilveri |