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(Nitrato-κ(2) O,O′)bis­(tryptanthrin-κN)silver(I)

In the crystal structure of the title compound, [Ag(NO(3))(C(15)H(8)N(2)O(2))(2)], tryptanthrin (indolo[2,1-b]quinazoline-6,12-dione) and silver nitrate form a 2:1 complex. The silver ion is surrounded by two tryptanthrin ligands, each coordinating through the N atoms, with Ag—N bond lengths of 2.24...

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Autores principales: Wu, Jie, Huang, Chao, Li, Guo-Qiang, Tian, Hai-Yan, Jiang, Ren-Wang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274910/
https://www.ncbi.nlm.nih.gov/pubmed/22346857
http://dx.doi.org/10.1107/S1600536812001821
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author Wu, Jie
Huang, Chao
Li, Guo-Qiang
Tian, Hai-Yan
Jiang, Ren-Wang
author_facet Wu, Jie
Huang, Chao
Li, Guo-Qiang
Tian, Hai-Yan
Jiang, Ren-Wang
author_sort Wu, Jie
collection PubMed
description In the crystal structure of the title compound, [Ag(NO(3))(C(15)H(8)N(2)O(2))(2)], tryptanthrin (indolo[2,1-b]quinazoline-6,12-dione) and silver nitrate form a 2:1 complex. The silver ion is surrounded by two tryptanthrin ligands, each coordinating through the N atoms, with Ag—N bond lengths of 2.247 (3) and 2.264 (3) Å, and an anionic nitrate ligand coordinating through two O atoms, with Ag—O bond lengths of 2.499 (3) and 2.591 (3) Å. The N—Ag—N plane and the O—Ag—O plane are roughly perpendicular, making a dihedral angle of 81.6 (2)°. In the crystal, C—H⋯O inter­actions between aromatic H atoms and keto and nitrate O atoms as well as π–π inter­actions [centroid-centroid distance = 3.706 (4) Å] give rise to a three-dimensional network.
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spelling pubmed-32749102012-02-15 (Nitrato-κ(2) O,O′)bis­(tryptanthrin-κN)silver(I) Wu, Jie Huang, Chao Li, Guo-Qiang Tian, Hai-Yan Jiang, Ren-Wang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the crystal structure of the title compound, [Ag(NO(3))(C(15)H(8)N(2)O(2))(2)], tryptanthrin (indolo[2,1-b]quinazoline-6,12-dione) and silver nitrate form a 2:1 complex. The silver ion is surrounded by two tryptanthrin ligands, each coordinating through the N atoms, with Ag—N bond lengths of 2.247 (3) and 2.264 (3) Å, and an anionic nitrate ligand coordinating through two O atoms, with Ag—O bond lengths of 2.499 (3) and 2.591 (3) Å. The N—Ag—N plane and the O—Ag—O plane are roughly perpendicular, making a dihedral angle of 81.6 (2)°. In the crystal, C—H⋯O inter­actions between aromatic H atoms and keto and nitrate O atoms as well as π–π inter­actions [centroid-centroid distance = 3.706 (4) Å] give rise to a three-dimensional network. International Union of Crystallography 2012-01-21 /pmc/articles/PMC3274910/ /pubmed/22346857 http://dx.doi.org/10.1107/S1600536812001821 Text en © Wu et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wu, Jie
Huang, Chao
Li, Guo-Qiang
Tian, Hai-Yan
Jiang, Ren-Wang
(Nitrato-κ(2) O,O′)bis­(tryptanthrin-κN)silver(I)
title (Nitrato-κ(2) O,O′)bis­(tryptanthrin-κN)silver(I)
title_full (Nitrato-κ(2) O,O′)bis­(tryptanthrin-κN)silver(I)
title_fullStr (Nitrato-κ(2) O,O′)bis­(tryptanthrin-κN)silver(I)
title_full_unstemmed (Nitrato-κ(2) O,O′)bis­(tryptanthrin-κN)silver(I)
title_short (Nitrato-κ(2) O,O′)bis­(tryptanthrin-κN)silver(I)
title_sort (nitrato-κ(2) o,o′)bis­(tryptanthrin-κn)silver(i)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274910/
https://www.ncbi.nlm.nih.gov/pubmed/22346857
http://dx.doi.org/10.1107/S1600536812001821
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