Poly[aqua­[μ(3)-4-carb­oxy-2-(pyridin-4-yl)-1H-imidazole-5-carboxyl­ato-κ(5) N (1),O (5):N (3),O (4):N (2)]nickel(II)]

The water-coordinated Ni(2+) cation in the title compound, [Ni(C(10)H(5)N(3)O(4))(H(2)O)](n), assumes an octa­hedral NiN(3)O(3) coord­ination mode and is N,O-chelated by two deprotonated 2-(pyridin-4-yl)-1H-imidazole-4,5-dicarb­oxy­lic acid (HPyImDC(2−)) ligands, forming a layer structure extending...

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Detalles Bibliográficos
Autores principales: Jing, Xue-Min, Gong, Shu-zhe, Xiao, Li-Wei
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274911/
https://www.ncbi.nlm.nih.gov/pubmed/22346858
http://dx.doi.org/10.1107/S1600536812001900
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author Jing, Xue-Min
Gong, Shu-zhe
Xiao, Li-Wei
author_facet Jing, Xue-Min
Gong, Shu-zhe
Xiao, Li-Wei
author_sort Jing, Xue-Min
collection PubMed
description The water-coordinated Ni(2+) cation in the title compound, [Ni(C(10)H(5)N(3)O(4))(H(2)O)](n), assumes an octa­hedral NiN(3)O(3) coord­ination mode and is N,O-chelated by two deprotonated 2-(pyridin-4-yl)-1H-imidazole-4,5-dicarb­oxy­lic acid (HPyImDC(2−)) ligands, forming a layer structure extending in the bc plane. The chains are arranged along the b-axis direction, forming a layer structure extending in the bc plane. O—H⋯O hydrogen bonding between the layers results in the formation of a three-dimensional supra­molecular framework. The structure is isotypic with the Zn analogue [Li et al. (2009). Cryst. Growth Des. 6, 3423–3431].
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spelling pubmed-32749112012-02-15 Poly[aqua­[μ(3)-4-carb­oxy-2-(pyridin-4-yl)-1H-imidazole-5-carboxyl­ato-κ(5) N (1),O (5):N (3),O (4):N (2)]nickel(II)] Jing, Xue-Min Gong, Shu-zhe Xiao, Li-Wei Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The water-coordinated Ni(2+) cation in the title compound, [Ni(C(10)H(5)N(3)O(4))(H(2)O)](n), assumes an octa­hedral NiN(3)O(3) coord­ination mode and is N,O-chelated by two deprotonated 2-(pyridin-4-yl)-1H-imidazole-4,5-dicarb­oxy­lic acid (HPyImDC(2−)) ligands, forming a layer structure extending in the bc plane. The chains are arranged along the b-axis direction, forming a layer structure extending in the bc plane. O—H⋯O hydrogen bonding between the layers results in the formation of a three-dimensional supra­molecular framework. The structure is isotypic with the Zn analogue [Li et al. (2009). Cryst. Growth Des. 6, 3423–3431]. International Union of Crystallography 2012-01-21 /pmc/articles/PMC3274911/ /pubmed/22346858 http://dx.doi.org/10.1107/S1600536812001900 Text en © Jing et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Jing, Xue-Min
Gong, Shu-zhe
Xiao, Li-Wei
Poly[aqua­[μ(3)-4-carb­oxy-2-(pyridin-4-yl)-1H-imidazole-5-carboxyl­ato-κ(5) N (1),O (5):N (3),O (4):N (2)]nickel(II)]
title Poly[aqua­[μ(3)-4-carb­oxy-2-(pyridin-4-yl)-1H-imidazole-5-carboxyl­ato-κ(5) N (1),O (5):N (3),O (4):N (2)]nickel(II)]
title_full Poly[aqua­[μ(3)-4-carb­oxy-2-(pyridin-4-yl)-1H-imidazole-5-carboxyl­ato-κ(5) N (1),O (5):N (3),O (4):N (2)]nickel(II)]
title_fullStr Poly[aqua­[μ(3)-4-carb­oxy-2-(pyridin-4-yl)-1H-imidazole-5-carboxyl­ato-κ(5) N (1),O (5):N (3),O (4):N (2)]nickel(II)]
title_full_unstemmed Poly[aqua­[μ(3)-4-carb­oxy-2-(pyridin-4-yl)-1H-imidazole-5-carboxyl­ato-κ(5) N (1),O (5):N (3),O (4):N (2)]nickel(II)]
title_short Poly[aqua­[μ(3)-4-carb­oxy-2-(pyridin-4-yl)-1H-imidazole-5-carboxyl­ato-κ(5) N (1),O (5):N (3),O (4):N (2)]nickel(II)]
title_sort poly[aqua­[μ(3)-4-carb­oxy-2-(pyridin-4-yl)-1h-imidazole-5-carboxyl­ato-κ(5) n (1),o (5):n (3),o (4):n (2)]nickel(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274911/
https://www.ncbi.nlm.nih.gov/pubmed/22346858
http://dx.doi.org/10.1107/S1600536812001900
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AT xiaoliwei polyaquam34carboxy2pyridin4yl1himidazole5carboxylatok5n1o5n3o4n2nickelii

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