trans-Tetra­kis(1-allyl-1H-imidazole-κN (3))bis­(thio­cyanato-κN)nickel(II)

The structure of the title compound, [Ni(NCS)(2)(C(6)H(8)N(2))(4)], consists of isolated mol­ecules of [Ni(NCS)(2)(Aim)(4)] (Aim = 1-allyl­imidazole), which contain a distorted octa­hedral NiN(6) chromophore. The NCS(−) anions are trans and four N atoms from the 1-allyl­imidazole ligands define the...

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Detalles Bibliográficos
Autores principales: Zheng, Shao-Mei, Jin, Yan-Ling
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274912/
https://www.ncbi.nlm.nih.gov/pubmed/22346859
http://dx.doi.org/10.1107/S1600536812001584
Descripción
Sumario:The structure of the title compound, [Ni(NCS)(2)(C(6)H(8)N(2))(4)], consists of isolated mol­ecules of [Ni(NCS)(2)(Aim)(4)] (Aim = 1-allyl­imidazole), which contain a distorted octa­hedral NiN(6) chromophore. The NCS(−) anions are trans and four N atoms from the 1-allyl­imidazole ligands define the equatorial plane. The mean Mn—N(Aim) and Mn—N(NCS) distances are 2.105 (2) and 2.098 (2) Å, respectively. Weak C—H⋯N inter­actions contribute to the crystal packing stability.

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