trans-Tetra­kis(1-allyl-1H-imidazole-κN (3))bis­(thio­cyanato-κN)nickel(II)

The structure of the title compound, [Ni(NCS)(2)(C(6)H(8)N(2))(4)], consists of isolated mol­ecules of [Ni(NCS)(2)(Aim)(4)] (Aim = 1-allyl­imidazole), which contain a distorted octa­hedral NiN(6) chromophore. The NCS(−) anions are trans and four N atoms from the 1-allyl­imidazole ligands define the...

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Detalles Bibliográficos
Autores principales: Zheng, Shao-Mei, Jin, Yan-Ling
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274912/
https://www.ncbi.nlm.nih.gov/pubmed/22346859
http://dx.doi.org/10.1107/S1600536812001584
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author Zheng, Shao-Mei
Jin, Yan-Ling
author_facet Zheng, Shao-Mei
Jin, Yan-Ling
author_sort Zheng, Shao-Mei
collection PubMed
description The structure of the title compound, [Ni(NCS)(2)(C(6)H(8)N(2))(4)], consists of isolated mol­ecules of [Ni(NCS)(2)(Aim)(4)] (Aim = 1-allyl­imidazole), which contain a distorted octa­hedral NiN(6) chromophore. The NCS(−) anions are trans and four N atoms from the 1-allyl­imidazole ligands define the equatorial plane. The mean Mn—N(Aim) and Mn—N(NCS) distances are 2.105 (2) and 2.098 (2) Å, respectively. Weak C—H⋯N inter­actions contribute to the crystal packing stability.
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spelling pubmed-32749122012-02-15 trans-Tetra­kis(1-allyl-1H-imidazole-κN (3))bis­(thio­cyanato-κN)nickel(II) Zheng, Shao-Mei Jin, Yan-Ling Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The structure of the title compound, [Ni(NCS)(2)(C(6)H(8)N(2))(4)], consists of isolated mol­ecules of [Ni(NCS)(2)(Aim)(4)] (Aim = 1-allyl­imidazole), which contain a distorted octa­hedral NiN(6) chromophore. The NCS(−) anions are trans and four N atoms from the 1-allyl­imidazole ligands define the equatorial plane. The mean Mn—N(Aim) and Mn—N(NCS) distances are 2.105 (2) and 2.098 (2) Å, respectively. Weak C—H⋯N inter­actions contribute to the crystal packing stability. International Union of Crystallography 2012-01-21 /pmc/articles/PMC3274912/ /pubmed/22346859 http://dx.doi.org/10.1107/S1600536812001584 Text en © Zheng and Jin 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zheng, Shao-Mei
Jin, Yan-Ling
trans-Tetra­kis(1-allyl-1H-imidazole-κN (3))bis­(thio­cyanato-κN)nickel(II)
title trans-Tetra­kis(1-allyl-1H-imidazole-κN (3))bis­(thio­cyanato-κN)nickel(II)
title_full trans-Tetra­kis(1-allyl-1H-imidazole-κN (3))bis­(thio­cyanato-κN)nickel(II)
title_fullStr trans-Tetra­kis(1-allyl-1H-imidazole-κN (3))bis­(thio­cyanato-κN)nickel(II)
title_full_unstemmed trans-Tetra­kis(1-allyl-1H-imidazole-κN (3))bis­(thio­cyanato-κN)nickel(II)
title_short trans-Tetra­kis(1-allyl-1H-imidazole-κN (3))bis­(thio­cyanato-κN)nickel(II)
title_sort trans-tetra­kis(1-allyl-1h-imidazole-κn (3))bis­(thio­cyanato-κn)nickel(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274912/
https://www.ncbi.nlm.nih.gov/pubmed/22346859
http://dx.doi.org/10.1107/S1600536812001584
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