{3,14-Dimethyl-2,6,13,17-tetra­aza­tricyclo­[16.4.0.0(7,12)]docosane-κ(4) N,N′,N′′,N′′′)bis­(nitrato-κO)copper(II)

The Cu(II) atom in the title compound, [Cu(NO(3))(2)(C(20)H(40)N(4))], is N,N′,N′′,N′′′-chelated by the macrocyclic ligand: the four N atoms form a square, above and below which are located the O atoms of the nitrate ions. The metal atom exists in a tetra­gonally distorted octa­hedron, on a special...

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Detalles Bibliográficos
Autores principales: Choi, Jong-Ha, Subhan, Md Abdus, Ng, Seik Weng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274913/
https://www.ncbi.nlm.nih.gov/pubmed/22346860
http://dx.doi.org/10.1107/S1600536812001845
Descripción
Sumario:The Cu(II) atom in the title compound, [Cu(NO(3))(2)(C(20)H(40)N(4))], is N,N′,N′′,N′′′-chelated by the macrocyclic ligand: the four N atoms form a square, above and below which are located the O atoms of the nitrate ions. The metal atom exists in a tetra­gonally distorted octa­hedron, on a special position of [Image: see text] site symmetry. One of the amino groups is hydrogen bonded to an O atom of the nitrate ion. The other amino group is hydrogen bonded to O atom of an adjacent mol­ecule, generating a supra­molecular dimeric hydrogen-bonded dinuclear aggregate.

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