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{3,14-Dimethyl-2,6,13,17-tetraazatricyclo[16.4.0.0(7,12)]docosane-κ(4) N,N′,N′′,N′′′)bis(nitrato-κO)copper(II)
The Cu(II) atom in the title compound, [Cu(NO(3))(2)(C(20)H(40)N(4))], is N,N′,N′′,N′′′-chelated by the macrocyclic ligand: the four N atoms form a square, above and below which are located the O atoms of the nitrate ions. The metal atom exists in a tetragonally distorted octahedron, on a special...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2012
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274913/ https://www.ncbi.nlm.nih.gov/pubmed/22346860 http://dx.doi.org/10.1107/S1600536812001845 |
| _version_ | 1782223134155341824 |
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| author | Choi, Jong-Ha Subhan, Md Abdus Ng, Seik Weng |
| author_facet | Choi, Jong-Ha Subhan, Md Abdus Ng, Seik Weng |
| author_sort | Choi, Jong-Ha |
| collection | PubMed |
| description | The Cu(II) atom in the title compound, [Cu(NO(3))(2)(C(20)H(40)N(4))], is N,N′,N′′,N′′′-chelated by the macrocyclic ligand: the four N atoms form a square, above and below which are located the O atoms of the nitrate ions. The metal atom exists in a tetragonally distorted octahedron, on a special position of [Image: see text] site symmetry. One of the amino groups is hydrogen bonded to an O atom of the nitrate ion. The other amino group is hydrogen bonded to O atom of an adjacent molecule, generating a supramolecular dimeric hydrogen-bonded dinuclear aggregate. |
| format | Online Article Text |
| id | pubmed-3274913 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2012 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-32749132012-02-15 {3,14-Dimethyl-2,6,13,17-tetraazatricyclo[16.4.0.0(7,12)]docosane-κ(4) N,N′,N′′,N′′′)bis(nitrato-κO)copper(II) Choi, Jong-Ha Subhan, Md Abdus Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Cu(II) atom in the title compound, [Cu(NO(3))(2)(C(20)H(40)N(4))], is N,N′,N′′,N′′′-chelated by the macrocyclic ligand: the four N atoms form a square, above and below which are located the O atoms of the nitrate ions. The metal atom exists in a tetragonally distorted octahedron, on a special position of [Image: see text] site symmetry. One of the amino groups is hydrogen bonded to an O atom of the nitrate ion. The other amino group is hydrogen bonded to O atom of an adjacent molecule, generating a supramolecular dimeric hydrogen-bonded dinuclear aggregate. International Union of Crystallography 2012-01-21 /pmc/articles/PMC3274913/ /pubmed/22346860 http://dx.doi.org/10.1107/S1600536812001845 Text en © Choi et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Choi, Jong-Ha Subhan, Md Abdus Ng, Seik Weng {3,14-Dimethyl-2,6,13,17-tetraazatricyclo[16.4.0.0(7,12)]docosane-κ(4) N,N′,N′′,N′′′)bis(nitrato-κO)copper(II) |
| title | {3,14-Dimethyl-2,6,13,17-tetraazatricyclo[16.4.0.0(7,12)]docosane-κ(4)
N,N′,N′′,N′′′)bis(nitrato-κO)copper(II) |
| title_full | {3,14-Dimethyl-2,6,13,17-tetraazatricyclo[16.4.0.0(7,12)]docosane-κ(4)
N,N′,N′′,N′′′)bis(nitrato-κO)copper(II) |
| title_fullStr | {3,14-Dimethyl-2,6,13,17-tetraazatricyclo[16.4.0.0(7,12)]docosane-κ(4)
N,N′,N′′,N′′′)bis(nitrato-κO)copper(II) |
| title_full_unstemmed | {3,14-Dimethyl-2,6,13,17-tetraazatricyclo[16.4.0.0(7,12)]docosane-κ(4)
N,N′,N′′,N′′′)bis(nitrato-κO)copper(II) |
| title_short | {3,14-Dimethyl-2,6,13,17-tetraazatricyclo[16.4.0.0(7,12)]docosane-κ(4)
N,N′,N′′,N′′′)bis(nitrato-κO)copper(II) |
| title_sort | {3,14-dimethyl-2,6,13,17-tetraazatricyclo[16.4.0.0(7,12)]docosane-κ(4)
n,n′,n′′,n′′′)bis(nitrato-κo)copper(ii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274913/ https://www.ncbi.nlm.nih.gov/pubmed/22346860 http://dx.doi.org/10.1107/S1600536812001845 |
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