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Bis[(1S,1′S)-1,1′-(4-amino-4H-1,2,4-triazole-3,5-diyl)diethanol-κN (1)]bis(nitrato-κO)zinc
In the title homochiral mononuclear compound, [Zn(NO(3))(2)(C(6)H(12)N(4)O(2))(2)], the Zn(II) atom is located on a twofold rotation axis and coordinated by two N atoms from two ligands and two O atoms from two NO(3) (−) anions, adopting a distorted tetrahedral coordination geometry. The compound i...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2012
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274914/ https://www.ncbi.nlm.nih.gov/pubmed/22346861 http://dx.doi.org/10.1107/S1600536812001754 |
| _version_ | 1782223134397562880 |
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| author | Liu, Xun-Gao Shen, Liang Cai, Qi-Suo Luo, Ma |
| author_facet | Liu, Xun-Gao Shen, Liang Cai, Qi-Suo Luo, Ma |
| author_sort | Liu, Xun-Gao |
| collection | PubMed |
| description | In the title homochiral mononuclear compound, [Zn(NO(3))(2)(C(6)H(12)N(4)O(2))(2)], the Zn(II) atom is located on a twofold rotation axis and coordinated by two N atoms from two ligands and two O atoms from two NO(3) (−) anions, adopting a distorted tetrahedral coordination geometry. The compound is enantiomerically pure and corresponds to the S diastereoisomer, with the optical activity originating from the chiral ligand. In the crystal, molecules are connected into three-dimensional supramolecular networks through O—H⋯O, O—H⋯N and N—H⋯O hydrogen bonds. |
| format | Online Article Text |
| id | pubmed-3274914 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2012 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-32749142012-02-15 Bis[(1S,1′S)-1,1′-(4-amino-4H-1,2,4-triazole-3,5-diyl)diethanol-κN (1)]bis(nitrato-κO)zinc Liu, Xun-Gao Shen, Liang Cai, Qi-Suo Luo, Ma Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title homochiral mononuclear compound, [Zn(NO(3))(2)(C(6)H(12)N(4)O(2))(2)], the Zn(II) atom is located on a twofold rotation axis and coordinated by two N atoms from two ligands and two O atoms from two NO(3) (−) anions, adopting a distorted tetrahedral coordination geometry. The compound is enantiomerically pure and corresponds to the S diastereoisomer, with the optical activity originating from the chiral ligand. In the crystal, molecules are connected into three-dimensional supramolecular networks through O—H⋯O, O—H⋯N and N—H⋯O hydrogen bonds. International Union of Crystallography 2012-01-21 /pmc/articles/PMC3274914/ /pubmed/22346861 http://dx.doi.org/10.1107/S1600536812001754 Text en © Liu et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Liu, Xun-Gao Shen, Liang Cai, Qi-Suo Luo, Ma Bis[(1S,1′S)-1,1′-(4-amino-4H-1,2,4-triazole-3,5-diyl)diethanol-κN (1)]bis(nitrato-κO)zinc |
| title | Bis[(1S,1′S)-1,1′-(4-amino-4H-1,2,4-triazole-3,5-diyl)diethanol-κN
(1)]bis(nitrato-κO)zinc |
| title_full | Bis[(1S,1′S)-1,1′-(4-amino-4H-1,2,4-triazole-3,5-diyl)diethanol-κN
(1)]bis(nitrato-κO)zinc |
| title_fullStr | Bis[(1S,1′S)-1,1′-(4-amino-4H-1,2,4-triazole-3,5-diyl)diethanol-κN
(1)]bis(nitrato-κO)zinc |
| title_full_unstemmed | Bis[(1S,1′S)-1,1′-(4-amino-4H-1,2,4-triazole-3,5-diyl)diethanol-κN
(1)]bis(nitrato-κO)zinc |
| title_short | Bis[(1S,1′S)-1,1′-(4-amino-4H-1,2,4-triazole-3,5-diyl)diethanol-κN
(1)]bis(nitrato-κO)zinc |
| title_sort | bis[(1s,1′s)-1,1′-(4-amino-4h-1,2,4-triazole-3,5-diyl)diethanol-κn
(1)]bis(nitrato-κo)zinc |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274914/ https://www.ncbi.nlm.nih.gov/pubmed/22346861 http://dx.doi.org/10.1107/S1600536812001754 |
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