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{4,4′,6,6′-Tetra­chloro-2,2′-[2,2-dimethyl­propane-1,3-diylbis(nitrilo­methanylyl­idene)]}nickel(II)

In the title compound, [Ni(C(19)H(16)Cl(4)N(2)O(2))], the Ni(II) ion is in a distorted square-planar environment coordinated by two N atoms and two O atoms of the tetra­dentate ligand. The dihedral angle between the benzene rings is 24.8 (2)°. In the crystal, mol­ecules are linked into chains along...

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Detalles Bibliográficos
Autores principales: Kargar, Hadi, Kia, Reza, Abbasian, Saeideh, Tahir, Muhammad Nawaz
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274915/
https://www.ncbi.nlm.nih.gov/pubmed/22346862
http://dx.doi.org/10.1107/S1600536812002085
Descripción
Sumario:In the title compound, [Ni(C(19)H(16)Cl(4)N(2)O(2))], the Ni(II) ion is in a distorted square-planar environment coordinated by two N atoms and two O atoms of the tetra­dentate ligand. The dihedral angle between the benzene rings is 24.8 (2)°. In the crystal, mol­ecules are linked into chains along the b axis by weak C—H⋯O and C—H⋯Cl inter­actions. An inter­molecular Cl⋯Cl [3.4564 (19) Å] inter­action is present which is shorter than the sum of the van der Waals radii of Cl atoms (3.50 Å).