{4,4′,6,6′-Tetra­chloro-2,2′-[2,2-dimethyl­propane-1,3-diylbis(nitrilo­methanylyl­idene)]}nickel(II)

In the title compound, [Ni(C(19)H(16)Cl(4)N(2)O(2))], the Ni(II) ion is in a distorted square-planar environment coordinated by two N atoms and two O atoms of the tetra­dentate ligand. The dihedral angle between the benzene rings is 24.8 (2)°. In the crystal, mol­ecules are linked into chains along...

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Detalles Bibliográficos
Autores principales: Kargar, Hadi, Kia, Reza, Abbasian, Saeideh, Tahir, Muhammad Nawaz
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274915/
https://www.ncbi.nlm.nih.gov/pubmed/22346862
http://dx.doi.org/10.1107/S1600536812002085
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author Kargar, Hadi
Kia, Reza
Abbasian, Saeideh
Tahir, Muhammad Nawaz
author_facet Kargar, Hadi
Kia, Reza
Abbasian, Saeideh
Tahir, Muhammad Nawaz
author_sort Kargar, Hadi
collection PubMed
description In the title compound, [Ni(C(19)H(16)Cl(4)N(2)O(2))], the Ni(II) ion is in a distorted square-planar environment coordinated by two N atoms and two O atoms of the tetra­dentate ligand. The dihedral angle between the benzene rings is 24.8 (2)°. In the crystal, mol­ecules are linked into chains along the b axis by weak C—H⋯O and C—H⋯Cl inter­actions. An inter­molecular Cl⋯Cl [3.4564 (19) Å] inter­action is present which is shorter than the sum of the van der Waals radii of Cl atoms (3.50 Å).
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spelling pubmed-32749152012-02-15 {4,4′,6,6′-Tetra­chloro-2,2′-[2,2-dimethyl­propane-1,3-diylbis(nitrilo­methanylyl­idene)]}nickel(II) Kargar, Hadi Kia, Reza Abbasian, Saeideh Tahir, Muhammad Nawaz Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Ni(C(19)H(16)Cl(4)N(2)O(2))], the Ni(II) ion is in a distorted square-planar environment coordinated by two N atoms and two O atoms of the tetra­dentate ligand. The dihedral angle between the benzene rings is 24.8 (2)°. In the crystal, mol­ecules are linked into chains along the b axis by weak C—H⋯O and C—H⋯Cl inter­actions. An inter­molecular Cl⋯Cl [3.4564 (19) Å] inter­action is present which is shorter than the sum of the van der Waals radii of Cl atoms (3.50 Å). International Union of Crystallography 2012-01-21 /pmc/articles/PMC3274915/ /pubmed/22346862 http://dx.doi.org/10.1107/S1600536812002085 Text en © Kargar et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Kargar, Hadi
Kia, Reza
Abbasian, Saeideh
Tahir, Muhammad Nawaz
{4,4′,6,6′-Tetra­chloro-2,2′-[2,2-dimethyl­propane-1,3-diylbis(nitrilo­methanylyl­idene)]}nickel(II)
title {4,4′,6,6′-Tetra­chloro-2,2′-[2,2-dimethyl­propane-1,3-diylbis(nitrilo­methanylyl­idene)]}nickel(II)
title_full {4,4′,6,6′-Tetra­chloro-2,2′-[2,2-dimethyl­propane-1,3-diylbis(nitrilo­methanylyl­idene)]}nickel(II)
title_fullStr {4,4′,6,6′-Tetra­chloro-2,2′-[2,2-dimethyl­propane-1,3-diylbis(nitrilo­methanylyl­idene)]}nickel(II)
title_full_unstemmed {4,4′,6,6′-Tetra­chloro-2,2′-[2,2-dimethyl­propane-1,3-diylbis(nitrilo­methanylyl­idene)]}nickel(II)
title_short {4,4′,6,6′-Tetra­chloro-2,2′-[2,2-dimethyl­propane-1,3-diylbis(nitrilo­methanylyl­idene)]}nickel(II)
title_sort {4,4′,6,6′-tetra­chloro-2,2′-[2,2-dimethyl­propane-1,3-diylbis(nitrilo­methanylyl­idene)]}nickel(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274915/
https://www.ncbi.nlm.nih.gov/pubmed/22346862
http://dx.doi.org/10.1107/S1600536812002085
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