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μ-Oxalato-κ(4) O (1),O (2):O (1′),O (2′)-bis[diaqua(2,2′-bipyridyl-κ(2) N,N′)zinc] bis[2-(1H-benzotriazol-1-yl)acetate] hexahydrate
The asymmetric unit of the title compound, [Zn(2)(C(2)O(4))(C(10)H(8)N(2))(2)(H(2)O)(4)](C(8)H(6)N(3)O(2))(2)·6H(2)O, contains one half of the centrosymmetric binuclear cation, one anion and three water molecules. In the cation, the oxalate ligand bridges two Zn(II) ions in a bis-bidentate fashion,...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274917/ https://www.ncbi.nlm.nih.gov/pubmed/22346864 http://dx.doi.org/10.1107/S1600536812001778 |
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author | Zeng, Ling Wang, Qinglin |
author_facet | Zeng, Ling Wang, Qinglin |
author_sort | Zeng, Ling |
collection | PubMed |
description | The asymmetric unit of the title compound, [Zn(2)(C(2)O(4))(C(10)H(8)N(2))(2)(H(2)O)(4)](C(8)H(6)N(3)O(2))(2)·6H(2)O, contains one half of the centrosymmetric binuclear cation, one anion and three water molecules. In the cation, the oxalate ligand bridges two Zn(II) ions in a bis-bidentate fashion, so each Zn(II) ion is coordinated by two O atoms from the oxalate ligand, two N atoms from two 2,2′-bipyridine ligands and two water molecules in a distorted octahedral arrangement. The mean planes of the oxalate and 2,2′-bipyridine ligands form a dihedral angle of 80.0 (1)°. An extensive three-dimensional hydrogen-bonding network formed by classical O—H⋯O and O—H⋯N interactions consolidates the crystal packing. |
format | Online Article Text |
id | pubmed-3274917 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32749172012-02-15 μ-Oxalato-κ(4) O (1),O (2):O (1′),O (2′)-bis[diaqua(2,2′-bipyridyl-κ(2) N,N′)zinc] bis[2-(1H-benzotriazol-1-yl)acetate] hexahydrate Zeng, Ling Wang, Qinglin Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [Zn(2)(C(2)O(4))(C(10)H(8)N(2))(2)(H(2)O)(4)](C(8)H(6)N(3)O(2))(2)·6H(2)O, contains one half of the centrosymmetric binuclear cation, one anion and three water molecules. In the cation, the oxalate ligand bridges two Zn(II) ions in a bis-bidentate fashion, so each Zn(II) ion is coordinated by two O atoms from the oxalate ligand, two N atoms from two 2,2′-bipyridine ligands and two water molecules in a distorted octahedral arrangement. The mean planes of the oxalate and 2,2′-bipyridine ligands form a dihedral angle of 80.0 (1)°. An extensive three-dimensional hydrogen-bonding network formed by classical O—H⋯O and O—H⋯N interactions consolidates the crystal packing. International Union of Crystallography 2012-01-21 /pmc/articles/PMC3274917/ /pubmed/22346864 http://dx.doi.org/10.1107/S1600536812001778 Text en © Zeng and Wang 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Zeng, Ling Wang, Qinglin μ-Oxalato-κ(4) O (1),O (2):O (1′),O (2′)-bis[diaqua(2,2′-bipyridyl-κ(2) N,N′)zinc] bis[2-(1H-benzotriazol-1-yl)acetate] hexahydrate |
title | μ-Oxalato-κ(4)
O
(1),O
(2):O
(1′),O
(2′)-bis[diaqua(2,2′-bipyridyl-κ(2)
N,N′)zinc] bis[2-(1H-benzotriazol-1-yl)acetate] hexahydrate |
title_full | μ-Oxalato-κ(4)
O
(1),O
(2):O
(1′),O
(2′)-bis[diaqua(2,2′-bipyridyl-κ(2)
N,N′)zinc] bis[2-(1H-benzotriazol-1-yl)acetate] hexahydrate |
title_fullStr | μ-Oxalato-κ(4)
O
(1),O
(2):O
(1′),O
(2′)-bis[diaqua(2,2′-bipyridyl-κ(2)
N,N′)zinc] bis[2-(1H-benzotriazol-1-yl)acetate] hexahydrate |
title_full_unstemmed | μ-Oxalato-κ(4)
O
(1),O
(2):O
(1′),O
(2′)-bis[diaqua(2,2′-bipyridyl-κ(2)
N,N′)zinc] bis[2-(1H-benzotriazol-1-yl)acetate] hexahydrate |
title_short | μ-Oxalato-κ(4)
O
(1),O
(2):O
(1′),O
(2′)-bis[diaqua(2,2′-bipyridyl-κ(2)
N,N′)zinc] bis[2-(1H-benzotriazol-1-yl)acetate] hexahydrate |
title_sort | μ-oxalato-κ(4)
o
(1),o
(2):o
(1′),o
(2′)-bis[diaqua(2,2′-bipyridyl-κ(2)
n,n′)zinc] bis[2-(1h-benzotriazol-1-yl)acetate] hexahydrate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274917/ https://www.ncbi.nlm.nih.gov/pubmed/22346864 http://dx.doi.org/10.1107/S1600536812001778 |
work_keys_str_mv | AT zengling moxalatok4o1o2o1o2bisdiaqua22bipyridylk2nnzincbis21hbenzotriazol1ylacetatehexahydrate AT wangqinglin moxalatok4o1o2o1o2bisdiaqua22bipyridylk2nnzincbis21hbenzotriazol1ylacetatehexahydrate |