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μ-Oxalato-κ(4) O (1),O (2):O (1′),O (2′)-bis­[diaqua­(2,2′-bipyridyl-κ(2) N,N′)zinc] bis­[2-(1H-benzotriazol-1-yl)acetate] hexa­hydrate

The asymmetric unit of the title compound, [Zn(2)(C(2)O(4))(C(10)H(8)N(2))(2)(H(2)O)(4)](C(8)H(6)N(3)O(2))(2)·6H(2)O, contains one half of the centrosymmetric binuclear cation, one anion and three water mol­ecules. In the cation, the oxalate ligand bridges two Zn(II) ions in a bis-bidentate fashion,...

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Detalles Bibliográficos
Autores principales: Zeng, Ling, Wang, Qinglin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274917/
https://www.ncbi.nlm.nih.gov/pubmed/22346864
http://dx.doi.org/10.1107/S1600536812001778
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author Zeng, Ling
Wang, Qinglin
author_facet Zeng, Ling
Wang, Qinglin
author_sort Zeng, Ling
collection PubMed
description The asymmetric unit of the title compound, [Zn(2)(C(2)O(4))(C(10)H(8)N(2))(2)(H(2)O)(4)](C(8)H(6)N(3)O(2))(2)·6H(2)O, contains one half of the centrosymmetric binuclear cation, one anion and three water mol­ecules. In the cation, the oxalate ligand bridges two Zn(II) ions in a bis-bidentate fashion, so each Zn(II) ion is coordinated by two O atoms from the oxalate ligand, two N atoms from two 2,2′-bipyridine ligands and two water mol­ecules in a distorted octa­hedral arrangement. The mean planes of the oxalate and 2,2′-bipyridine ligands form a dihedral angle of 80.0 (1)°. An extensive three-dimensional hydrogen-bonding network formed by classical O—H⋯O and O—H⋯N inter­actions consolidates the crystal packing.
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spelling pubmed-32749172012-02-15 μ-Oxalato-κ(4) O (1),O (2):O (1′),O (2′)-bis­[diaqua­(2,2′-bipyridyl-κ(2) N,N′)zinc] bis­[2-(1H-benzotriazol-1-yl)acetate] hexa­hydrate Zeng, Ling Wang, Qinglin Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [Zn(2)(C(2)O(4))(C(10)H(8)N(2))(2)(H(2)O)(4)](C(8)H(6)N(3)O(2))(2)·6H(2)O, contains one half of the centrosymmetric binuclear cation, one anion and three water mol­ecules. In the cation, the oxalate ligand bridges two Zn(II) ions in a bis-bidentate fashion, so each Zn(II) ion is coordinated by two O atoms from the oxalate ligand, two N atoms from two 2,2′-bipyridine ligands and two water mol­ecules in a distorted octa­hedral arrangement. The mean planes of the oxalate and 2,2′-bipyridine ligands form a dihedral angle of 80.0 (1)°. An extensive three-dimensional hydrogen-bonding network formed by classical O—H⋯O and O—H⋯N inter­actions consolidates the crystal packing. International Union of Crystallography 2012-01-21 /pmc/articles/PMC3274917/ /pubmed/22346864 http://dx.doi.org/10.1107/S1600536812001778 Text en © Zeng and Wang 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zeng, Ling
Wang, Qinglin
μ-Oxalato-κ(4) O (1),O (2):O (1′),O (2′)-bis­[diaqua­(2,2′-bipyridyl-κ(2) N,N′)zinc] bis­[2-(1H-benzotriazol-1-yl)acetate] hexa­hydrate
title μ-Oxalato-κ(4) O (1),O (2):O (1′),O (2′)-bis­[diaqua­(2,2′-bipyridyl-κ(2) N,N′)zinc] bis­[2-(1H-benzotriazol-1-yl)acetate] hexa­hydrate
title_full μ-Oxalato-κ(4) O (1),O (2):O (1′),O (2′)-bis­[diaqua­(2,2′-bipyridyl-κ(2) N,N′)zinc] bis­[2-(1H-benzotriazol-1-yl)acetate] hexa­hydrate
title_fullStr μ-Oxalato-κ(4) O (1),O (2):O (1′),O (2′)-bis­[diaqua­(2,2′-bipyridyl-κ(2) N,N′)zinc] bis­[2-(1H-benzotriazol-1-yl)acetate] hexa­hydrate
title_full_unstemmed μ-Oxalato-κ(4) O (1),O (2):O (1′),O (2′)-bis­[diaqua­(2,2′-bipyridyl-κ(2) N,N′)zinc] bis­[2-(1H-benzotriazol-1-yl)acetate] hexa­hydrate
title_short μ-Oxalato-κ(4) O (1),O (2):O (1′),O (2′)-bis­[diaqua­(2,2′-bipyridyl-κ(2) N,N′)zinc] bis­[2-(1H-benzotriazol-1-yl)acetate] hexa­hydrate
title_sort μ-oxalato-κ(4) o (1),o (2):o (1′),o (2′)-bis­[diaqua­(2,2′-bipyridyl-κ(2) n,n′)zinc] bis­[2-(1h-benzotriazol-1-yl)acetate] hexa­hydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274917/
https://www.ncbi.nlm.nih.gov/pubmed/22346864
http://dx.doi.org/10.1107/S1600536812001778
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AT wangqinglin moxalatok4o1o2o1o2bisdiaqua22bipyridylk2nnzincbis21hbenzotriazol1ylacetatehexahydrate