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(Ferrocenylmethyl)trimethylammonium perchlorate
The asymmetric unit of the title complex, [Fe(C(5)H(5))(C(9)H(15)N)]ClO(4), contains one discrete (ferrocenylmethyl)trimethylammonium cation and one perchlorate anion. The anion is disordered over two sets of sites, with refined occupancies of 0.776 (8) and 0.224 (8). The distances from the Fe ato...
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Formato: | Online Artículo Texto |
Lenguaje: | English |
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International Union of Crystallography
2012
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274918/ https://www.ncbi.nlm.nih.gov/pubmed/22346865 http://dx.doi.org/10.1107/S1600536812002176 |
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author | Wang, Ying-Chun |
author_facet | Wang, Ying-Chun |
author_sort | Wang, Ying-Chun |
collection | PubMed |
description | The asymmetric unit of the title complex, [Fe(C(5)H(5))(C(9)H(15)N)]ClO(4), contains one discrete (ferrocenylmethyl)trimethylammonium cation and one perchlorate anion. The anion is disordered over two sets of sites, with refined occupancies of 0.776 (8) and 0.224 (8). The distances from the Fe atom to the centroids of the unsubstituted and substituted cyclopentadienyl (Cp) rings are 1.650 (1) and 1.640 (1) Å, respectively. The Cp rings form a dihedral angle of 2.66 (3)°. |
format | Online Article Text |
id | pubmed-3274918 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32749182012-02-15 (Ferrocenylmethyl)trimethylammonium perchlorate Wang, Ying-Chun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title complex, [Fe(C(5)H(5))(C(9)H(15)N)]ClO(4), contains one discrete (ferrocenylmethyl)trimethylammonium cation and one perchlorate anion. The anion is disordered over two sets of sites, with refined occupancies of 0.776 (8) and 0.224 (8). The distances from the Fe atom to the centroids of the unsubstituted and substituted cyclopentadienyl (Cp) rings are 1.650 (1) and 1.640 (1) Å, respectively. The Cp rings form a dihedral angle of 2.66 (3)°. International Union of Crystallography 2012-01-21 /pmc/articles/PMC3274918/ /pubmed/22346865 http://dx.doi.org/10.1107/S1600536812002176 Text en © Ying-Chun Wang 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Wang, Ying-Chun (Ferrocenylmethyl)trimethylammonium perchlorate |
title | (Ferrocenylmethyl)trimethylammonium perchlorate |
title_full | (Ferrocenylmethyl)trimethylammonium perchlorate |
title_fullStr | (Ferrocenylmethyl)trimethylammonium perchlorate |
title_full_unstemmed | (Ferrocenylmethyl)trimethylammonium perchlorate |
title_short | (Ferrocenylmethyl)trimethylammonium perchlorate |
title_sort | (ferrocenylmethyl)trimethylammonium perchlorate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274918/ https://www.ncbi.nlm.nih.gov/pubmed/22346865 http://dx.doi.org/10.1107/S1600536812002176 |
work_keys_str_mv | AT wangyingchun ferrocenylmethyltrimethylammoniumperchlorate |