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Bis(μ-3-hydroxybenzoato)-κ(3) O (1),O (1′):O (1);κ(3) O (1):O (1),O (1′)-bis[(3-hydroxybenzoato-κ(2) O,O′)(isonicotinamide-κN (1))cadmium] tetrahydrate
In the title centrosymmetric binuclear Cd(II) compound, [Cd(2)(C(7)H(5)O(3))(4)(C(6)H(6)N(2)O)(2)]·4H(2)O, the six-coordinated Cd(II) atom is chelated by the carboxylate groups of the two 3-hydroxybenzoate (HB) anions; the two monomeric units are bridged through the two O atoms of the two carboxy...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2012
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274919/ https://www.ncbi.nlm.nih.gov/pubmed/22346866 http://dx.doi.org/10.1107/S160053681200219X |
| _version_ | 1782223135568822272 |
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| author | Zaman, Ibrahim Göker Çaylak Delibaş, Nagihan Necefoğlu, Hacali Hökelek, Tuncer |
| author_facet | Zaman, Ibrahim Göker Çaylak Delibaş, Nagihan Necefoğlu, Hacali Hökelek, Tuncer |
| author_sort | Zaman, Ibrahim Göker |
| collection | PubMed |
| description | In the title centrosymmetric binuclear Cd(II) compound, [Cd(2)(C(7)H(5)O(3))(4)(C(6)H(6)N(2)O)(2)]·4H(2)O, the six-coordinated Cd(II) atom is chelated by the carboxylate groups of the two 3-hydroxybenzoate (HB) anions; the two monomeric units are bridged through the two O atoms of the two carboxylate groups. In the crystal, O—H⋯O, N—H⋯O and C—H⋯O hydrogen bonds link the molecules into a three-dimensional network. π–π Contacts between the pyridine rings and between the benzene rings [centroid-centroid distances = 3.770 (1), 3.769 (1) and 3.632 (1) Å] may further stabilize the structure. |
| format | Online Article Text |
| id | pubmed-3274919 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2012 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-32749192012-02-15 Bis(μ-3-hydroxybenzoato)-κ(3) O (1),O (1′):O (1);κ(3) O (1):O (1),O (1′)-bis[(3-hydroxybenzoato-κ(2) O,O′)(isonicotinamide-κN (1))cadmium] tetrahydrate Zaman, Ibrahim Göker Çaylak Delibaş, Nagihan Necefoğlu, Hacali Hökelek, Tuncer Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title centrosymmetric binuclear Cd(II) compound, [Cd(2)(C(7)H(5)O(3))(4)(C(6)H(6)N(2)O)(2)]·4H(2)O, the six-coordinated Cd(II) atom is chelated by the carboxylate groups of the two 3-hydroxybenzoate (HB) anions; the two monomeric units are bridged through the two O atoms of the two carboxylate groups. In the crystal, O—H⋯O, N—H⋯O and C—H⋯O hydrogen bonds link the molecules into a three-dimensional network. π–π Contacts between the pyridine rings and between the benzene rings [centroid-centroid distances = 3.770 (1), 3.769 (1) and 3.632 (1) Å] may further stabilize the structure. International Union of Crystallography 2012-01-21 /pmc/articles/PMC3274919/ /pubmed/22346866 http://dx.doi.org/10.1107/S160053681200219X Text en © Zaman et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Zaman, Ibrahim Göker Çaylak Delibaş, Nagihan Necefoğlu, Hacali Hökelek, Tuncer Bis(μ-3-hydroxybenzoato)-κ(3) O (1),O (1′):O (1);κ(3) O (1):O (1),O (1′)-bis[(3-hydroxybenzoato-κ(2) O,O′)(isonicotinamide-κN (1))cadmium] tetrahydrate |
| title | Bis(μ-3-hydroxybenzoato)-κ(3)
O
(1),O
(1′):O
(1);κ(3)
O
(1):O
(1),O
(1′)-bis[(3-hydroxybenzoato-κ(2)
O,O′)(isonicotinamide-κN
(1))cadmium] tetrahydrate |
| title_full | Bis(μ-3-hydroxybenzoato)-κ(3)
O
(1),O
(1′):O
(1);κ(3)
O
(1):O
(1),O
(1′)-bis[(3-hydroxybenzoato-κ(2)
O,O′)(isonicotinamide-κN
(1))cadmium] tetrahydrate |
| title_fullStr | Bis(μ-3-hydroxybenzoato)-κ(3)
O
(1),O
(1′):O
(1);κ(3)
O
(1):O
(1),O
(1′)-bis[(3-hydroxybenzoato-κ(2)
O,O′)(isonicotinamide-κN
(1))cadmium] tetrahydrate |
| title_full_unstemmed | Bis(μ-3-hydroxybenzoato)-κ(3)
O
(1),O
(1′):O
(1);κ(3)
O
(1):O
(1),O
(1′)-bis[(3-hydroxybenzoato-κ(2)
O,O′)(isonicotinamide-κN
(1))cadmium] tetrahydrate |
| title_short | Bis(μ-3-hydroxybenzoato)-κ(3)
O
(1),O
(1′):O
(1);κ(3)
O
(1):O
(1),O
(1′)-bis[(3-hydroxybenzoato-κ(2)
O,O′)(isonicotinamide-κN
(1))cadmium] tetrahydrate |
| title_sort | bis(μ-3-hydroxybenzoato)-κ(3)
o
(1),o
(1′):o
(1);κ(3)
o
(1):o
(1),o
(1′)-bis[(3-hydroxybenzoato-κ(2)
o,o′)(isonicotinamide-κn
(1))cadmium] tetrahydrate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274919/ https://www.ncbi.nlm.nih.gov/pubmed/22346866 http://dx.doi.org/10.1107/S160053681200219X |
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