Poly[μ(3)-β-alanine-aqua-μ(4)-sulfato-dilithium]

The title compound, [Li(2)(SO(4))(C(3)H(7)NO(2))(H(2)O)](n), is a coordination polymer in which the β-alanine residues remain in the zwitterionic form. The crystal structure consists of corrugated sheets of [LiO(4)] and [SO(4)] tetra­hedra parallel to (010) with the β-alanine mol­ecules located betw...

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Detalles Bibliográficos
Autores principales: Sweetlin, M. Daniel, Eapen, Shibu M., Perumal, S., Ramalingom, S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274924/
https://www.ncbi.nlm.nih.gov/pubmed/22346871
http://dx.doi.org/10.1107/S1600536812002115
Descripción
Sumario:The title compound, [Li(2)(SO(4))(C(3)H(7)NO(2))(H(2)O)](n), is a coordination polymer in which the β-alanine residues remain in the zwitterionic form. The crystal structure consists of corrugated sheets of [LiO(4)] and [SO(4)] tetra­hedra parallel to (010) with the β-alanine mol­ecules located between the sheets. The two independent Li(+) cations are four-coordinated by O atoms in a distorted tetra­hedral geometry. The crystal structure is formed by stacking of alternate organic and inorganic layers along the a axis. The crystal structure is further stabilized by N—H⋯O hydrogen bonds.

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