Poly[μ(3)-β-alanine-aqua-μ(4)-sulfato-dilithium]

The title compound, [Li(2)(SO(4))(C(3)H(7)NO(2))(H(2)O)](n), is a coordination polymer in which the β-alanine residues remain in the zwitterionic form. The crystal structure consists of corrugated sheets of [LiO(4)] and [SO(4)] tetra­hedra parallel to (010) with the β-alanine mol­ecules located betw...

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Detalles Bibliográficos
Autores principales: Sweetlin, M. Daniel, Eapen, Shibu M., Perumal, S., Ramalingom, S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274924/
https://www.ncbi.nlm.nih.gov/pubmed/22346871
http://dx.doi.org/10.1107/S1600536812002115
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author Sweetlin, M. Daniel
Eapen, Shibu M.
Perumal, S.
Ramalingom, S.
author_facet Sweetlin, M. Daniel
Eapen, Shibu M.
Perumal, S.
Ramalingom, S.
author_sort Sweetlin, M. Daniel
collection PubMed
description The title compound, [Li(2)(SO(4))(C(3)H(7)NO(2))(H(2)O)](n), is a coordination polymer in which the β-alanine residues remain in the zwitterionic form. The crystal structure consists of corrugated sheets of [LiO(4)] and [SO(4)] tetra­hedra parallel to (010) with the β-alanine mol­ecules located between the sheets. The two independent Li(+) cations are four-coordinated by O atoms in a distorted tetra­hedral geometry. The crystal structure is formed by stacking of alternate organic and inorganic layers along the a axis. The crystal structure is further stabilized by N—H⋯O hydrogen bonds.
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spelling pubmed-32749242012-02-15 Poly[μ(3)-β-alanine-aqua-μ(4)-sulfato-dilithium] Sweetlin, M. Daniel Eapen, Shibu M. Perumal, S. Ramalingom, S. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Li(2)(SO(4))(C(3)H(7)NO(2))(H(2)O)](n), is a coordination polymer in which the β-alanine residues remain in the zwitterionic form. The crystal structure consists of corrugated sheets of [LiO(4)] and [SO(4)] tetra­hedra parallel to (010) with the β-alanine mol­ecules located between the sheets. The two independent Li(+) cations are four-coordinated by O atoms in a distorted tetra­hedral geometry. The crystal structure is formed by stacking of alternate organic and inorganic layers along the a axis. The crystal structure is further stabilized by N—H⋯O hydrogen bonds. International Union of Crystallography 2012-01-25 /pmc/articles/PMC3274924/ /pubmed/22346871 http://dx.doi.org/10.1107/S1600536812002115 Text en © Sweetlin et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Sweetlin, M. Daniel
Eapen, Shibu M.
Perumal, S.
Ramalingom, S.
Poly[μ(3)-β-alanine-aqua-μ(4)-sulfato-dilithium]
title Poly[μ(3)-β-alanine-aqua-μ(4)-sulfato-dilithium]
title_full Poly[μ(3)-β-alanine-aqua-μ(4)-sulfato-dilithium]
title_fullStr Poly[μ(3)-β-alanine-aqua-μ(4)-sulfato-dilithium]
title_full_unstemmed Poly[μ(3)-β-alanine-aqua-μ(4)-sulfato-dilithium]
title_short Poly[μ(3)-β-alanine-aqua-μ(4)-sulfato-dilithium]
title_sort poly[μ(3)-β-alanine-aqua-μ(4)-sulfato-dilithium]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274924/
https://www.ncbi.nlm.nih.gov/pubmed/22346871
http://dx.doi.org/10.1107/S1600536812002115
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