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Trichlorido{2-dimethoxymethyl-4-methyl-6-[(quinolin-8-yl)iminomethyl]phenolato-κ(3) N,N′,O (1)}tin(IV)
In the title compound, [Sn(C(20)H(19)N(2)O(3))Cl(3)], the Sn(IV) ion is surrounded by a tridentate monoanionic Schiff base and by three meridional chloride ions in a six-coordinated distorted octahedral geometry. The Sn—Cl bond [2.366 (2) Å] trans to nitrogen is shorter than the others [2.438 (2)...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274925/ https://www.ncbi.nlm.nih.gov/pubmed/22346872 http://dx.doi.org/10.1107/S1600536812002528 |
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author | Kawamoto, Keisuke Shibahara, Takashi |
author_facet | Kawamoto, Keisuke Shibahara, Takashi |
author_sort | Kawamoto, Keisuke |
collection | PubMed |
description | In the title compound, [Sn(C(20)H(19)N(2)O(3))Cl(3)], the Sn(IV) ion is surrounded by a tridentate monoanionic Schiff base and by three meridional chloride ions in a six-coordinated distorted octahedral geometry. The Sn—Cl bond [2.366 (2) Å] trans to nitrogen is shorter than the others [2.438 (2) and 2.414 (2) Å]. The N—Sn—N angle [76.19 (11)°] is smaller than the O—Sn—N angle [87.89 (10)°] in the Schiff base ligand. No classical intermolecular hydrogen-bonding interactions are observed. The crystal packing exhibits π–π stacking interactions, with a distance of 3.595 (2) Å between the centroids of the phenolate ring and the benzene ring of the quinoline group of inversion-related molecules. |
format | Online Article Text |
id | pubmed-3274925 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32749252012-02-15 Trichlorido{2-dimethoxymethyl-4-methyl-6-[(quinolin-8-yl)iminomethyl]phenolato-κ(3) N,N′,O (1)}tin(IV) Kawamoto, Keisuke Shibahara, Takashi Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Sn(C(20)H(19)N(2)O(3))Cl(3)], the Sn(IV) ion is surrounded by a tridentate monoanionic Schiff base and by three meridional chloride ions in a six-coordinated distorted octahedral geometry. The Sn—Cl bond [2.366 (2) Å] trans to nitrogen is shorter than the others [2.438 (2) and 2.414 (2) Å]. The N—Sn—N angle [76.19 (11)°] is smaller than the O—Sn—N angle [87.89 (10)°] in the Schiff base ligand. No classical intermolecular hydrogen-bonding interactions are observed. The crystal packing exhibits π–π stacking interactions, with a distance of 3.595 (2) Å between the centroids of the phenolate ring and the benzene ring of the quinoline group of inversion-related molecules. International Union of Crystallography 2012-01-31 /pmc/articles/PMC3274925/ /pubmed/22346872 http://dx.doi.org/10.1107/S1600536812002528 Text en © Kawamoto and Shibahara 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Kawamoto, Keisuke Shibahara, Takashi Trichlorido{2-dimethoxymethyl-4-methyl-6-[(quinolin-8-yl)iminomethyl]phenolato-κ(3) N,N′,O (1)}tin(IV) |
title | Trichlorido{2-dimethoxymethyl-4-methyl-6-[(quinolin-8-yl)iminomethyl]phenolato-κ(3)
N,N′,O
(1)}tin(IV) |
title_full | Trichlorido{2-dimethoxymethyl-4-methyl-6-[(quinolin-8-yl)iminomethyl]phenolato-κ(3)
N,N′,O
(1)}tin(IV) |
title_fullStr | Trichlorido{2-dimethoxymethyl-4-methyl-6-[(quinolin-8-yl)iminomethyl]phenolato-κ(3)
N,N′,O
(1)}tin(IV) |
title_full_unstemmed | Trichlorido{2-dimethoxymethyl-4-methyl-6-[(quinolin-8-yl)iminomethyl]phenolato-κ(3)
N,N′,O
(1)}tin(IV) |
title_short | Trichlorido{2-dimethoxymethyl-4-methyl-6-[(quinolin-8-yl)iminomethyl]phenolato-κ(3)
N,N′,O
(1)}tin(IV) |
title_sort | trichlorido{2-dimethoxymethyl-4-methyl-6-[(quinolin-8-yl)iminomethyl]phenolato-κ(3)
n,n′,o
(1)}tin(iv) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274925/ https://www.ncbi.nlm.nih.gov/pubmed/22346872 http://dx.doi.org/10.1107/S1600536812002528 |
work_keys_str_mv | AT kawamotokeisuke trichlorido2dimethoxymethyl4methyl6quinolin8yliminomethylphenolatok3nno1tiniv AT shibaharatakashi trichlorido2dimethoxymethyl4methyl6quinolin8yliminomethylphenolatok3nno1tiniv |