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Trichlorido{2-dimeth­oxy­methyl-4-methyl-6-[(quinolin-8-yl)imino­meth­yl]phenolato-κ(3) N,N′,O (1)}tin(IV)

In the title compound, [Sn(C(20)H(19)N(2)O(3))Cl(3)], the Sn(IV) ion is surrounded by a tridentate monoanionic Schiff base and by three meridional chloride ions in a six-coordinated distorted octa­hedral geometry. The Sn—Cl bond [2.366 (2) Å] trans to nitro­gen is shorter than the others [2.438 (2)...

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Detalles Bibliográficos
Autores principales: Kawamoto, Keisuke, Shibahara, Takashi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274925/
https://www.ncbi.nlm.nih.gov/pubmed/22346872
http://dx.doi.org/10.1107/S1600536812002528
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author Kawamoto, Keisuke
Shibahara, Takashi
author_facet Kawamoto, Keisuke
Shibahara, Takashi
author_sort Kawamoto, Keisuke
collection PubMed
description In the title compound, [Sn(C(20)H(19)N(2)O(3))Cl(3)], the Sn(IV) ion is surrounded by a tridentate monoanionic Schiff base and by three meridional chloride ions in a six-coordinated distorted octa­hedral geometry. The Sn—Cl bond [2.366 (2) Å] trans to nitro­gen is shorter than the others [2.438 (2) and 2.414 (2) Å]. The N—Sn—N angle [76.19 (11)°] is smaller than the O—Sn—N angle [87.89 (10)°] in the Schiff base ligand. No classical inter­molecular hydrogen-bonding inter­actions are observed. The crystal packing exhibits π–π stacking inter­actions, with a distance of 3.595 (2) Å between the centroids of the phenolate ring and the benzene ring of the quinoline group of inversion-related mol­ecules.
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spelling pubmed-32749252012-02-15 Trichlorido{2-dimeth­oxy­methyl-4-methyl-6-[(quinolin-8-yl)imino­meth­yl]phenolato-κ(3) N,N′,O (1)}tin(IV) Kawamoto, Keisuke Shibahara, Takashi Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Sn(C(20)H(19)N(2)O(3))Cl(3)], the Sn(IV) ion is surrounded by a tridentate monoanionic Schiff base and by three meridional chloride ions in a six-coordinated distorted octa­hedral geometry. The Sn—Cl bond [2.366 (2) Å] trans to nitro­gen is shorter than the others [2.438 (2) and 2.414 (2) Å]. The N—Sn—N angle [76.19 (11)°] is smaller than the O—Sn—N angle [87.89 (10)°] in the Schiff base ligand. No classical inter­molecular hydrogen-bonding inter­actions are observed. The crystal packing exhibits π–π stacking inter­actions, with a distance of 3.595 (2) Å between the centroids of the phenolate ring and the benzene ring of the quinoline group of inversion-related mol­ecules. International Union of Crystallography 2012-01-31 /pmc/articles/PMC3274925/ /pubmed/22346872 http://dx.doi.org/10.1107/S1600536812002528 Text en © Kawamoto and Shibahara 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Kawamoto, Keisuke
Shibahara, Takashi
Trichlorido{2-dimeth­oxy­methyl-4-methyl-6-[(quinolin-8-yl)imino­meth­yl]phenolato-κ(3) N,N′,O (1)}tin(IV)
title Trichlorido{2-dimeth­oxy­methyl-4-methyl-6-[(quinolin-8-yl)imino­meth­yl]phenolato-κ(3) N,N′,O (1)}tin(IV)
title_full Trichlorido{2-dimeth­oxy­methyl-4-methyl-6-[(quinolin-8-yl)imino­meth­yl]phenolato-κ(3) N,N′,O (1)}tin(IV)
title_fullStr Trichlorido{2-dimeth­oxy­methyl-4-methyl-6-[(quinolin-8-yl)imino­meth­yl]phenolato-κ(3) N,N′,O (1)}tin(IV)
title_full_unstemmed Trichlorido{2-dimeth­oxy­methyl-4-methyl-6-[(quinolin-8-yl)imino­meth­yl]phenolato-κ(3) N,N′,O (1)}tin(IV)
title_short Trichlorido{2-dimeth­oxy­methyl-4-methyl-6-[(quinolin-8-yl)imino­meth­yl]phenolato-κ(3) N,N′,O (1)}tin(IV)
title_sort trichlorido{2-dimeth­oxy­methyl-4-methyl-6-[(quinolin-8-yl)imino­meth­yl]phenolato-κ(3) n,n′,o (1)}tin(iv)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274925/
https://www.ncbi.nlm.nih.gov/pubmed/22346872
http://dx.doi.org/10.1107/S1600536812002528
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