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Poly[[(μ(2)-di-3-pyridylmethanone-κ(2) N:N′)(μ(2)-hexafluorosilicato-κ(2) F:F′)copper(II)] dihydrate]
In the title complex, {[Cu(SiF(6))(C(11)H(8)N(2)O)(2)]·2H(2)O}(n), the Cu(II) atom adopts an N(4)F(2)-octahedral coordination geometry with four pyridine N atoms in the equatorial sites and two F atoms in the axial sites. The di-3-pyridylmethanone and hexafluorosilicate ligands act as bidentate...
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Formato: | Online Artículo Texto |
Lenguaje: | English |
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International Union of Crystallography
2012
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274926/ https://www.ncbi.nlm.nih.gov/pubmed/22346873 http://dx.doi.org/10.1107/S1600536812002267 |
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author | Yang, Yong-Li |
author_facet | Yang, Yong-Li |
author_sort | Yang, Yong-Li |
collection | PubMed |
description | In the title complex, {[Cu(SiF(6))(C(11)H(8)N(2)O)(2)]·2H(2)O}(n), the Cu(II) atom adopts an N(4)F(2)-octahedral coordination geometry with four pyridine N atoms in the equatorial sites and two F atoms in the axial sites. The di-3-pyridylmethanone and hexafluorosilicate ligands act as bidentate ligands, linking symmetry-related Cu(II) atoms. Water molecules form O—H⋯O and O—H⋯F hydrogen bonds with the di-3-pyridylmethanone and hexafluorosilicate ligands. The Cu(2+) and SiF(6) (2−) ions are each located on a twofold axis. |
format | Online Article Text |
id | pubmed-3274926 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32749262012-02-15 Poly[[(μ(2)-di-3-pyridylmethanone-κ(2) N:N′)(μ(2)-hexafluorosilicato-κ(2) F:F′)copper(II)] dihydrate] Yang, Yong-Li Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, {[Cu(SiF(6))(C(11)H(8)N(2)O)(2)]·2H(2)O}(n), the Cu(II) atom adopts an N(4)F(2)-octahedral coordination geometry with four pyridine N atoms in the equatorial sites and two F atoms in the axial sites. The di-3-pyridylmethanone and hexafluorosilicate ligands act as bidentate ligands, linking symmetry-related Cu(II) atoms. Water molecules form O—H⋯O and O—H⋯F hydrogen bonds with the di-3-pyridylmethanone and hexafluorosilicate ligands. The Cu(2+) and SiF(6) (2−) ions are each located on a twofold axis. International Union of Crystallography 2012-01-31 /pmc/articles/PMC3274926/ /pubmed/22346873 http://dx.doi.org/10.1107/S1600536812002267 Text en © Yong-Li Yang 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Yang, Yong-Li Poly[[(μ(2)-di-3-pyridylmethanone-κ(2) N:N′)(μ(2)-hexafluorosilicato-κ(2) F:F′)copper(II)] dihydrate] |
title | Poly[[(μ(2)-di-3-pyridylmethanone-κ(2)
N:N′)(μ(2)-hexafluorosilicato-κ(2)
F:F′)copper(II)] dihydrate] |
title_full | Poly[[(μ(2)-di-3-pyridylmethanone-κ(2)
N:N′)(μ(2)-hexafluorosilicato-κ(2)
F:F′)copper(II)] dihydrate] |
title_fullStr | Poly[[(μ(2)-di-3-pyridylmethanone-κ(2)
N:N′)(μ(2)-hexafluorosilicato-κ(2)
F:F′)copper(II)] dihydrate] |
title_full_unstemmed | Poly[[(μ(2)-di-3-pyridylmethanone-κ(2)
N:N′)(μ(2)-hexafluorosilicato-κ(2)
F:F′)copper(II)] dihydrate] |
title_short | Poly[[(μ(2)-di-3-pyridylmethanone-κ(2)
N:N′)(μ(2)-hexafluorosilicato-κ(2)
F:F′)copper(II)] dihydrate] |
title_sort | poly[[(μ(2)-di-3-pyridylmethanone-κ(2)
n:n′)(μ(2)-hexafluorosilicato-κ(2)
f:f′)copper(ii)] dihydrate] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274926/ https://www.ncbi.nlm.nih.gov/pubmed/22346873 http://dx.doi.org/10.1107/S1600536812002267 |
work_keys_str_mv | AT yangyongli polym2di3pyridylmethanonek2nnm2hexafluorosilicatok2ffcopperiidihydrate |