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Poly[[(μ(2)-di-3-pyridyl­methanone-κ(2) N:N′)(μ(2)-hexa­fluoro­silicato-κ(2) F:F′)copper(II)] dihydrate]

In the title complex, {[Cu(SiF(6))(C(11)H(8)N(2)O)(2)]·2H(2)O}(n), the Cu(II) atom adopts an N(4)F(2)-octa­hedral coordination geometry with four pyridine N atoms in the equatorial sites and two F atoms in the axial sites. The di-3-pyridyl­methanone and hexa­fluoro­silicate ligands act as bidentate...

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Autor principal: Yang, Yong-Li
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274926/
https://www.ncbi.nlm.nih.gov/pubmed/22346873
http://dx.doi.org/10.1107/S1600536812002267
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author Yang, Yong-Li
author_facet Yang, Yong-Li
author_sort Yang, Yong-Li
collection PubMed
description In the title complex, {[Cu(SiF(6))(C(11)H(8)N(2)O)(2)]·2H(2)O}(n), the Cu(II) atom adopts an N(4)F(2)-octa­hedral coordination geometry with four pyridine N atoms in the equatorial sites and two F atoms in the axial sites. The di-3-pyridyl­methanone and hexa­fluoro­silicate ligands act as bidentate ligands, linking symmetry-related Cu(II) atoms. Water mol­ecules form O—H⋯O and O—H⋯F hydrogen bonds with the di-3-pyridyl­methanone and hexa­fluoro­silicate ligands. The Cu(2+) and SiF(6) (2−) ions are each located on a twofold axis.
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spelling pubmed-32749262012-02-15 Poly[[(μ(2)-di-3-pyridyl­methanone-κ(2) N:N′)(μ(2)-hexa­fluoro­silicato-κ(2) F:F′)copper(II)] dihydrate] Yang, Yong-Li Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, {[Cu(SiF(6))(C(11)H(8)N(2)O)(2)]·2H(2)O}(n), the Cu(II) atom adopts an N(4)F(2)-octa­hedral coordination geometry with four pyridine N atoms in the equatorial sites and two F atoms in the axial sites. The di-3-pyridyl­methanone and hexa­fluoro­silicate ligands act as bidentate ligands, linking symmetry-related Cu(II) atoms. Water mol­ecules form O—H⋯O and O—H⋯F hydrogen bonds with the di-3-pyridyl­methanone and hexa­fluoro­silicate ligands. The Cu(2+) and SiF(6) (2−) ions are each located on a twofold axis. International Union of Crystallography 2012-01-31 /pmc/articles/PMC3274926/ /pubmed/22346873 http://dx.doi.org/10.1107/S1600536812002267 Text en © Yong-Li Yang 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Yang, Yong-Li
Poly[[(μ(2)-di-3-pyridyl­methanone-κ(2) N:N′)(μ(2)-hexa­fluoro­silicato-κ(2) F:F′)copper(II)] dihydrate]
title Poly[[(μ(2)-di-3-pyridyl­methanone-κ(2) N:N′)(μ(2)-hexa­fluoro­silicato-κ(2) F:F′)copper(II)] dihydrate]
title_full Poly[[(μ(2)-di-3-pyridyl­methanone-κ(2) N:N′)(μ(2)-hexa­fluoro­silicato-κ(2) F:F′)copper(II)] dihydrate]
title_fullStr Poly[[(μ(2)-di-3-pyridyl­methanone-κ(2) N:N′)(μ(2)-hexa­fluoro­silicato-κ(2) F:F′)copper(II)] dihydrate]
title_full_unstemmed Poly[[(μ(2)-di-3-pyridyl­methanone-κ(2) N:N′)(μ(2)-hexa­fluoro­silicato-κ(2) F:F′)copper(II)] dihydrate]
title_short Poly[[(μ(2)-di-3-pyridyl­methanone-κ(2) N:N′)(μ(2)-hexa­fluoro­silicato-κ(2) F:F′)copper(II)] dihydrate]
title_sort poly[[(μ(2)-di-3-pyridyl­methanone-κ(2) n:n′)(μ(2)-hexa­fluoro­silicato-κ(2) f:f′)copper(ii)] dihydrate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274926/
https://www.ncbi.nlm.nih.gov/pubmed/22346873
http://dx.doi.org/10.1107/S1600536812002267
work_keys_str_mv AT yangyongli polym2di3pyridylmethanonek2nnm2hexafluorosilicatok2ffcopperiidihydrate