catena-Poly[[lead(II)-bis­(μ(2)-quinolin-8-ol­ato)-κ(3) N,O:O;κ(3) O:N,O] N,N-di­methyl­formamide hemisolvate]

The asymmetric unit of the title compound, {[Pb(C(9)H(6)NO)(2)]·0.5C(3)H(7)NO}(n), comprises Pb(quinolate)(2) and half a dimethyl­formamide mol­ecule (which is disordered about a centre of inversion). The quinolate ligands N,O-chelate to a Pb(II) ion and simultaneously bridge a neighbouring Pb(II) i...

Descripción completa

Detalles Bibliográficos
Autores principales: Ghaemi, Akbar, Dadkhah, Zohreh, Ng, Seik Weng, Tiekink, Edward R. T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274927/
https://www.ncbi.nlm.nih.gov/pubmed/22346874
http://dx.doi.org/10.1107/S1600536812002796
_version_ 1782223137456259072
author Ghaemi, Akbar
Dadkhah, Zohreh
Ng, Seik Weng
Tiekink, Edward R. T.
author_facet Ghaemi, Akbar
Dadkhah, Zohreh
Ng, Seik Weng
Tiekink, Edward R. T.
author_sort Ghaemi, Akbar
collection PubMed
description The asymmetric unit of the title compound, {[Pb(C(9)H(6)NO)(2)]·0.5C(3)H(7)NO}(n), comprises Pb(quinolate)(2) and half a dimethyl­formamide mol­ecule (which is disordered about a centre of inversion). The quinolate ligands N,O-chelate to a Pb(II) ion and simultaneously bridge a neighbouring Pb(II) ion to form a polymeric chain along [100] comprising Pb-linked Pb(2)O(2) distorted rhombi. These chains pack to form a square grid, with the channels thus defined occupied by the disordered solvent mol­ecules.
format Online
Article
Text
id pubmed-3274927
institution National Center for Biotechnology Information
language English
publishDate 2012
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-32749272012-02-15 catena-Poly[[lead(II)-bis­(μ(2)-quinolin-8-ol­ato)-κ(3) N,O:O;κ(3) O:N,O] N,N-di­methyl­formamide hemisolvate] Ghaemi, Akbar Dadkhah, Zohreh Ng, Seik Weng Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, {[Pb(C(9)H(6)NO)(2)]·0.5C(3)H(7)NO}(n), comprises Pb(quinolate)(2) and half a dimethyl­formamide mol­ecule (which is disordered about a centre of inversion). The quinolate ligands N,O-chelate to a Pb(II) ion and simultaneously bridge a neighbouring Pb(II) ion to form a polymeric chain along [100] comprising Pb-linked Pb(2)O(2) distorted rhombi. These chains pack to form a square grid, with the channels thus defined occupied by the disordered solvent mol­ecules. International Union of Crystallography 2012-01-31 /pmc/articles/PMC3274927/ /pubmed/22346874 http://dx.doi.org/10.1107/S1600536812002796 Text en © Ghaemi et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Ghaemi, Akbar
Dadkhah, Zohreh
Ng, Seik Weng
Tiekink, Edward R. T.
catena-Poly[[lead(II)-bis­(μ(2)-quinolin-8-ol­ato)-κ(3) N,O:O;κ(3) O:N,O] N,N-di­methyl­formamide hemisolvate]
title catena-Poly[[lead(II)-bis­(μ(2)-quinolin-8-ol­ato)-κ(3) N,O:O;κ(3) O:N,O] N,N-di­methyl­formamide hemisolvate]
title_full catena-Poly[[lead(II)-bis­(μ(2)-quinolin-8-ol­ato)-κ(3) N,O:O;κ(3) O:N,O] N,N-di­methyl­formamide hemisolvate]
title_fullStr catena-Poly[[lead(II)-bis­(μ(2)-quinolin-8-ol­ato)-κ(3) N,O:O;κ(3) O:N,O] N,N-di­methyl­formamide hemisolvate]
title_full_unstemmed catena-Poly[[lead(II)-bis­(μ(2)-quinolin-8-ol­ato)-κ(3) N,O:O;κ(3) O:N,O] N,N-di­methyl­formamide hemisolvate]
title_short catena-Poly[[lead(II)-bis­(μ(2)-quinolin-8-ol­ato)-κ(3) N,O:O;κ(3) O:N,O] N,N-di­methyl­formamide hemisolvate]
title_sort catena-poly[[lead(ii)-bis­(μ(2)-quinolin-8-ol­ato)-κ(3) n,o:o;κ(3) o:n,o] n,n-di­methyl­formamide hemisolvate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274927/
https://www.ncbi.nlm.nih.gov/pubmed/22346874
http://dx.doi.org/10.1107/S1600536812002796
work_keys_str_mv AT ghaemiakbar catenapolyleadiibism2quinolin8olatok3nook3ononndimethylformamidehemisolvate
AT dadkhahzohreh catenapolyleadiibism2quinolin8olatok3nook3ononndimethylformamidehemisolvate
AT ngseikweng catenapolyleadiibism2quinolin8olatok3nook3ononndimethylformamidehemisolvate
AT tiekinkedwardrt catenapolyleadiibism2quinolin8olatok3nook3ononndimethylformamidehemisolvate

Ejemplares similares