Poly[[diaqua­tetra­kis­(μ(2)-benzene-1,4-di­carbonitrile-κ(2) N:N′)iron(II)] bis­[tetra­chlorido­ferrate(III)] nitro­methane tetra­solvate]

In the title compound, {[Fe(II)(C(8)H(4)N(2))(2)(H(2)O)(2)][Fe(III)Cl(4)](2)·4CH(3)NO(2)}(n), the Fe(II) and Fe(III) ions are hexa- and tetra­coordinated, respectively. Each unique benzene-1,4-dicarbonitrile mol­ecule lies across a crystallographic inversion centre and bridges two Fe(II) ions (each...

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Detalles Bibliográficos
Autores principales: Prommon, Pimonrat, Promseenong, Pinyada, Chainok, Kittipong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274928/
https://www.ncbi.nlm.nih.gov/pubmed/22346875
http://dx.doi.org/10.1107/S1600536812002486
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author Prommon, Pimonrat
Promseenong, Pinyada
Chainok, Kittipong
author_facet Prommon, Pimonrat
Promseenong, Pinyada
Chainok, Kittipong
author_sort Prommon, Pimonrat
collection PubMed
description In the title compound, {[Fe(II)(C(8)H(4)N(2))(2)(H(2)O)(2)][Fe(III)Cl(4)](2)·4CH(3)NO(2)}(n), the Fe(II) and Fe(III) ions are hexa- and tetra­coordinated, respectively. Each unique benzene-1,4-dicarbonitrile mol­ecule lies across a crystallographic inversion centre and bridges two Fe(II) ions (each situated on an inversion centre), generating two-dimensional (4,4) square grid layers. The tetra­chloridoferrate(III) anions and nitro­methane solvent mol­ecules lie between the square grid layers and are further link to the adjacent layers into a three-dimensional supra­molecular structure through O—H⋯Cl and O—H⋯O hydrogen bonds.
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spelling pubmed-32749282012-02-15 Poly[[diaqua­tetra­kis­(μ(2)-benzene-1,4-di­carbonitrile-κ(2) N:N′)iron(II)] bis­[tetra­chlorido­ferrate(III)] nitro­methane tetra­solvate] Prommon, Pimonrat Promseenong, Pinyada Chainok, Kittipong Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, {[Fe(II)(C(8)H(4)N(2))(2)(H(2)O)(2)][Fe(III)Cl(4)](2)·4CH(3)NO(2)}(n), the Fe(II) and Fe(III) ions are hexa- and tetra­coordinated, respectively. Each unique benzene-1,4-dicarbonitrile mol­ecule lies across a crystallographic inversion centre and bridges two Fe(II) ions (each situated on an inversion centre), generating two-dimensional (4,4) square grid layers. The tetra­chloridoferrate(III) anions and nitro­methane solvent mol­ecules lie between the square grid layers and are further link to the adjacent layers into a three-dimensional supra­molecular structure through O—H⋯Cl and O—H⋯O hydrogen bonds. International Union of Crystallography 2012-01-31 /pmc/articles/PMC3274928/ /pubmed/22346875 http://dx.doi.org/10.1107/S1600536812002486 Text en © Prommon et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Prommon, Pimonrat
Promseenong, Pinyada
Chainok, Kittipong
Poly[[diaqua­tetra­kis­(μ(2)-benzene-1,4-di­carbonitrile-κ(2) N:N′)iron(II)] bis­[tetra­chlorido­ferrate(III)] nitro­methane tetra­solvate]
title Poly[[diaqua­tetra­kis­(μ(2)-benzene-1,4-di­carbonitrile-κ(2) N:N′)iron(II)] bis­[tetra­chlorido­ferrate(III)] nitro­methane tetra­solvate]
title_full Poly[[diaqua­tetra­kis­(μ(2)-benzene-1,4-di­carbonitrile-κ(2) N:N′)iron(II)] bis­[tetra­chlorido­ferrate(III)] nitro­methane tetra­solvate]
title_fullStr Poly[[diaqua­tetra­kis­(μ(2)-benzene-1,4-di­carbonitrile-κ(2) N:N′)iron(II)] bis­[tetra­chlorido­ferrate(III)] nitro­methane tetra­solvate]
title_full_unstemmed Poly[[diaqua­tetra­kis­(μ(2)-benzene-1,4-di­carbonitrile-κ(2) N:N′)iron(II)] bis­[tetra­chlorido­ferrate(III)] nitro­methane tetra­solvate]
title_short Poly[[diaqua­tetra­kis­(μ(2)-benzene-1,4-di­carbonitrile-κ(2) N:N′)iron(II)] bis­[tetra­chlorido­ferrate(III)] nitro­methane tetra­solvate]
title_sort poly[[diaqua­tetra­kis­(μ(2)-benzene-1,4-di­carbonitrile-κ(2) n:n′)iron(ii)] bis­[tetra­chlorido­ferrate(iii)] nitro­methane tetra­solvate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274928/
https://www.ncbi.nlm.nih.gov/pubmed/22346875
http://dx.doi.org/10.1107/S1600536812002486
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AT chainokkittipong polydiaquatetrakism2benzene14dicarbonitrilek2nnironiibistetrachloridoferrateiiinitromethanetetrasolvate

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