Diaqua­dichloridomethyl­phenyl­tin(IV)–1,4,7,10,13-penta­oxacyclo­penta­decane (1/1)

The asymmetric unit of the title cocrystal, [Sn(CH(3))(C(6)H(5))Cl(2)(H(2)O)(2)]·C(10)H(20)O(5), contains two independent for­mula units. The organotin molecules exhibit a six-coordinate metal atom and are linked to the crown ether molecules by water–crown ether O—H⋯O hydrogen bonds into a linear ch...

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Detalles Bibliográficos
Autores principales: Vafaee, Marzieh, Amini, Mostafa M., Ng, Seik Weng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274929/
https://www.ncbi.nlm.nih.gov/pubmed/22346876
http://dx.doi.org/10.1107/S1600536812002693
Descripción
Sumario:The asymmetric unit of the title cocrystal, [Sn(CH(3))(C(6)H(5))Cl(2)(H(2)O)(2)]·C(10)H(20)O(5), contains two independent for­mula units. The organotin molecules exhibit a six-coordinate metal atom and are linked to the crown ether molecules by water–crown ether O—H⋯O hydrogen bonds into a linear chain running along [101]. Each coordinated water mol­ecule forms a pair of hydrogen bonds to the same crown ether; for the crown ether mol­ecules, only four of the five O atoms are engaged in hydrogen-bonding inter­actions. The metal ions show a distorted trans-C(2)SnCl(2)O(2) octa­hedral coordination geometry [C—Sn—C = 175.3 (1) and 178.9 (1)°].

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