Diaqua­dichloridomethyl­phenyl­tin(IV)–1,4,7,10,13-penta­oxacyclo­penta­decane (1/1)

The asymmetric unit of the title cocrystal, [Sn(CH(3))(C(6)H(5))Cl(2)(H(2)O)(2)]·C(10)H(20)O(5), contains two independent for­mula units. The organotin molecules exhibit a six-coordinate metal atom and are linked to the crown ether molecules by water–crown ether O—H⋯O hydrogen bonds into a linear ch...

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Detalles Bibliográficos
Autores principales: Vafaee, Marzieh, Amini, Mostafa M., Ng, Seik Weng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274929/
https://www.ncbi.nlm.nih.gov/pubmed/22346876
http://dx.doi.org/10.1107/S1600536812002693
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author Vafaee, Marzieh
Amini, Mostafa M.
Ng, Seik Weng
author_facet Vafaee, Marzieh
Amini, Mostafa M.
Ng, Seik Weng
author_sort Vafaee, Marzieh
collection PubMed
description The asymmetric unit of the title cocrystal, [Sn(CH(3))(C(6)H(5))Cl(2)(H(2)O)(2)]·C(10)H(20)O(5), contains two independent for­mula units. The organotin molecules exhibit a six-coordinate metal atom and are linked to the crown ether molecules by water–crown ether O—H⋯O hydrogen bonds into a linear chain running along [101]. Each coordinated water mol­ecule forms a pair of hydrogen bonds to the same crown ether; for the crown ether mol­ecules, only four of the five O atoms are engaged in hydrogen-bonding inter­actions. The metal ions show a distorted trans-C(2)SnCl(2)O(2) octa­hedral coordination geometry [C—Sn—C = 175.3 (1) and 178.9 (1)°].
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spelling pubmed-32749292012-02-15 Diaqua­dichloridomethyl­phenyl­tin(IV)–1,4,7,10,13-penta­oxacyclo­penta­decane (1/1) Vafaee, Marzieh Amini, Mostafa M. Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title cocrystal, [Sn(CH(3))(C(6)H(5))Cl(2)(H(2)O)(2)]·C(10)H(20)O(5), contains two independent for­mula units. The organotin molecules exhibit a six-coordinate metal atom and are linked to the crown ether molecules by water–crown ether O—H⋯O hydrogen bonds into a linear chain running along [101]. Each coordinated water mol­ecule forms a pair of hydrogen bonds to the same crown ether; for the crown ether mol­ecules, only four of the five O atoms are engaged in hydrogen-bonding inter­actions. The metal ions show a distorted trans-C(2)SnCl(2)O(2) octa­hedral coordination geometry [C—Sn—C = 175.3 (1) and 178.9 (1)°]. International Union of Crystallography 2012-01-31 /pmc/articles/PMC3274929/ /pubmed/22346876 http://dx.doi.org/10.1107/S1600536812002693 Text en © Vafaee et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Vafaee, Marzieh
Amini, Mostafa M.
Ng, Seik Weng
Diaqua­dichloridomethyl­phenyl­tin(IV)–1,4,7,10,13-penta­oxacyclo­penta­decane (1/1)
title Diaqua­dichloridomethyl­phenyl­tin(IV)–1,4,7,10,13-penta­oxacyclo­penta­decane (1/1)
title_full Diaqua­dichloridomethyl­phenyl­tin(IV)–1,4,7,10,13-penta­oxacyclo­penta­decane (1/1)
title_fullStr Diaqua­dichloridomethyl­phenyl­tin(IV)–1,4,7,10,13-penta­oxacyclo­penta­decane (1/1)
title_full_unstemmed Diaqua­dichloridomethyl­phenyl­tin(IV)–1,4,7,10,13-penta­oxacyclo­penta­decane (1/1)
title_short Diaqua­dichloridomethyl­phenyl­tin(IV)–1,4,7,10,13-penta­oxacyclo­penta­decane (1/1)
title_sort diaqua­dichloridomethyl­phenyl­tin(iv)–1,4,7,10,13-penta­oxacyclo­penta­decane (1/1)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274929/
https://www.ncbi.nlm.nih.gov/pubmed/22346876
http://dx.doi.org/10.1107/S1600536812002693
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