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catena-Poly[[[bis[μ-3-(4-carboxyphenoxy)propionato]-κ(3) O (1),O (1′):O (1);κ(3) O (1):O (1),O (1′)-bis[aqua(N,N-dimethylformamide-κO)cadmium]]-μ-4,4′-bipyridine-κ(2) N:N′] dinitrate]
In the title coordination polymer, {[Cd(2)(C(10)H(9)O(5))(2)(C(10)H(8)N(2))(2)(C(3)H(7)NO)(2)(H(2)O)(2)](NO(3))(2)}(n), the 3-(4-carboxyphenoxy)propionate monoanion O,O′-chelates to a Cd(II) cation through the aliphatic carboxylate end. One of these O atoms is also connected to the metal cation...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274930/ https://www.ncbi.nlm.nih.gov/pubmed/22346877 http://dx.doi.org/10.1107/S1600536812002991 |
Sumario: | In the title coordination polymer, {[Cd(2)(C(10)H(9)O(5))(2)(C(10)H(8)N(2))(2)(C(3)H(7)NO)(2)(H(2)O)(2)](NO(3))(2)}(n), the 3-(4-carboxyphenoxy)propionate monoanion O,O′-chelates to a Cd(II) cation through the aliphatic carboxylate end. One of these O atoms is also connected to the metal cation from an inversion-related metal atom. The five O atoms bonded to the metal centre form a pentagon, above and below which are located the N atoms of the 4,4′-bipyridine molecules. The polycationic ribbon propagates along the b axis of the unit cell. The (aromatic) carboxyl end of the monoanion connects adjacent ribbons into a layer motif in the (102) plane. The nitrate ions are hydrogen bonded to the layer. The geometry of the Cd(II) atom is a trans-N(2)O(5)Cd pentagonal bipyramid. |
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