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catena-Poly[[[bis[μ-3-(4-carboxyphenoxy)propionato]-κ(3) O (1),O (1′):O (1);κ(3) O (1):O (1),O (1′)-bis[aqua(N,N-dimethylformamide-κO)cadmium]]-μ-4,4′-bipyridine-κ(2) N:N′] dinitrate]
In the title coordination polymer, {[Cd(2)(C(10)H(9)O(5))(2)(C(10)H(8)N(2))(2)(C(3)H(7)NO)(2)(H(2)O)(2)](NO(3))(2)}(n), the 3-(4-carboxyphenoxy)propionate monoanion O,O′-chelates to a Cd(II) cation through the aliphatic carboxylate end. One of these O atoms is also connected to the metal cation...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2012
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274930/ https://www.ncbi.nlm.nih.gov/pubmed/22346877 http://dx.doi.org/10.1107/S1600536812002991 |
| _version_ | 1782223138155659264 |
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| author | Gao, Shan Ng, Seik Weng |
| author_facet | Gao, Shan Ng, Seik Weng |
| author_sort | Gao, Shan |
| collection | PubMed |
| description | In the title coordination polymer, {[Cd(2)(C(10)H(9)O(5))(2)(C(10)H(8)N(2))(2)(C(3)H(7)NO)(2)(H(2)O)(2)](NO(3))(2)}(n), the 3-(4-carboxyphenoxy)propionate monoanion O,O′-chelates to a Cd(II) cation through the aliphatic carboxylate end. One of these O atoms is also connected to the metal cation from an inversion-related metal atom. The five O atoms bonded to the metal centre form a pentagon, above and below which are located the N atoms of the 4,4′-bipyridine molecules. The polycationic ribbon propagates along the b axis of the unit cell. The (aromatic) carboxyl end of the monoanion connects adjacent ribbons into a layer motif in the (102) plane. The nitrate ions are hydrogen bonded to the layer. The geometry of the Cd(II) atom is a trans-N(2)O(5)Cd pentagonal bipyramid. |
| format | Online Article Text |
| id | pubmed-3274930 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2012 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-32749302012-02-15 catena-Poly[[[bis[μ-3-(4-carboxyphenoxy)propionato]-κ(3) O (1),O (1′):O (1);κ(3) O (1):O (1),O (1′)-bis[aqua(N,N-dimethylformamide-κO)cadmium]]-μ-4,4′-bipyridine-κ(2) N:N′] dinitrate] Gao, Shan Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title coordination polymer, {[Cd(2)(C(10)H(9)O(5))(2)(C(10)H(8)N(2))(2)(C(3)H(7)NO)(2)(H(2)O)(2)](NO(3))(2)}(n), the 3-(4-carboxyphenoxy)propionate monoanion O,O′-chelates to a Cd(II) cation through the aliphatic carboxylate end. One of these O atoms is also connected to the metal cation from an inversion-related metal atom. The five O atoms bonded to the metal centre form a pentagon, above and below which are located the N atoms of the 4,4′-bipyridine molecules. The polycationic ribbon propagates along the b axis of the unit cell. The (aromatic) carboxyl end of the monoanion connects adjacent ribbons into a layer motif in the (102) plane. The nitrate ions are hydrogen bonded to the layer. The geometry of the Cd(II) atom is a trans-N(2)O(5)Cd pentagonal bipyramid. International Union of Crystallography 2012-01-31 /pmc/articles/PMC3274930/ /pubmed/22346877 http://dx.doi.org/10.1107/S1600536812002991 Text en © Gao and Ng 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Gao, Shan Ng, Seik Weng catena-Poly[[[bis[μ-3-(4-carboxyphenoxy)propionato]-κ(3) O (1),O (1′):O (1);κ(3) O (1):O (1),O (1′)-bis[aqua(N,N-dimethylformamide-κO)cadmium]]-μ-4,4′-bipyridine-κ(2) N:N′] dinitrate] |
| title |
catena-Poly[[[bis[μ-3-(4-carboxyphenoxy)propionato]-κ(3)
O
(1),O
(1′):O
(1);κ(3)
O
(1):O
(1),O
(1′)-bis[aqua(N,N-dimethylformamide-κO)cadmium]]-μ-4,4′-bipyridine-κ(2)
N:N′] dinitrate] |
| title_full |
catena-Poly[[[bis[μ-3-(4-carboxyphenoxy)propionato]-κ(3)
O
(1),O
(1′):O
(1);κ(3)
O
(1):O
(1),O
(1′)-bis[aqua(N,N-dimethylformamide-κO)cadmium]]-μ-4,4′-bipyridine-κ(2)
N:N′] dinitrate] |
| title_fullStr |
catena-Poly[[[bis[μ-3-(4-carboxyphenoxy)propionato]-κ(3)
O
(1),O
(1′):O
(1);κ(3)
O
(1):O
(1),O
(1′)-bis[aqua(N,N-dimethylformamide-κO)cadmium]]-μ-4,4′-bipyridine-κ(2)
N:N′] dinitrate] |
| title_full_unstemmed |
catena-Poly[[[bis[μ-3-(4-carboxyphenoxy)propionato]-κ(3)
O
(1),O
(1′):O
(1);κ(3)
O
(1):O
(1),O
(1′)-bis[aqua(N,N-dimethylformamide-κO)cadmium]]-μ-4,4′-bipyridine-κ(2)
N:N′] dinitrate] |
| title_short |
catena-Poly[[[bis[μ-3-(4-carboxyphenoxy)propionato]-κ(3)
O
(1),O
(1′):O
(1);κ(3)
O
(1):O
(1),O
(1′)-bis[aqua(N,N-dimethylformamide-κO)cadmium]]-μ-4,4′-bipyridine-κ(2)
N:N′] dinitrate] |
| title_sort | catena-poly[[[bis[μ-3-(4-carboxyphenoxy)propionato]-κ(3)
o
(1),o
(1′):o
(1);κ(3)
o
(1):o
(1),o
(1′)-bis[aqua(n,n-dimethylformamide-κo)cadmium]]-μ-4,4′-bipyridine-κ(2)
n:n′] dinitrate] |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274930/ https://www.ncbi.nlm.nih.gov/pubmed/22346877 http://dx.doi.org/10.1107/S1600536812002991 |
| work_keys_str_mv | AT gaoshan catenapolybism34carboxyphenoxypropionatok3o1o1o1k3o1o1o1bisaquanndimethylformamidekocadmiumm44bipyridinek2nndinitrate AT ngseikweng catenapolybism34carboxyphenoxypropionatok3o1o1o1k3o1o1o1bisaquanndimethylformamidekocadmiumm44bipyridinek2nndinitrate |