{2-[Bis(2,4-di-tert-butyl­phen­oxy)phosphan­yloxy-κP]-3,5-di-tert-butyl­phenyl-κC (1)}[(1,2,5,6-η)-cyclo­octa-1,5-diene]rhodium(I) toluene monosolvate

The reaction of (η(3)-all­yl)[(1,2,5,6-η)-cyclo­octa-1,5-diene]rhodium(I) with tris­(2,4-di-tert-butyl­phen­yl)phosphite in toluene produces the title compound, [Rh(C(42)H(62)O(3)P)(C(8)H(12))]·C(7)H(8), by spontaneous metallation at one of the nonsubstituted phenyl ortho-C atoms of the phosphite mo...

Descripción completa

Detalles Bibliográficos
Autores principales: Selent, Detlef, Spannenberg, Anke, Börner, Armin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274931/
https://www.ncbi.nlm.nih.gov/pubmed/22346878
http://dx.doi.org/10.1107/S1600536812002851
_version_ 1782223138402074624
author Selent, Detlef
Spannenberg, Anke
Börner, Armin
author_facet Selent, Detlef
Spannenberg, Anke
Börner, Armin
author_sort Selent, Detlef
collection PubMed
description The reaction of (η(3)-all­yl)[(1,2,5,6-η)-cyclo­octa-1,5-diene]rhodium(I) with tris­(2,4-di-tert-butyl­phen­yl)phosphite in toluene produces the title compound, [Rh(C(42)H(62)O(3)P)(C(8)H(12))]·C(7)H(8), by spontaneous metallation at one of the nonsubstituted phenyl ortho-C atoms of the phosphite mol­ecule. The coordination geometry at the Rh(I) ion is distorted square-planar. The toluene solvent mol­ecule is disordered over two different orientations, with site-occupation factors of 0.810 (2) and 0.190 (2).
format Online
Article
Text
id pubmed-3274931
institution National Center for Biotechnology Information
language English
publishDate 2012
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-32749312012-02-15 {2-[Bis(2,4-di-tert-butyl­phen­oxy)phosphan­yloxy-κP]-3,5-di-tert-butyl­phenyl-κC (1)}[(1,2,5,6-η)-cyclo­octa-1,5-diene]rhodium(I) toluene monosolvate Selent, Detlef Spannenberg, Anke Börner, Armin Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The reaction of (η(3)-all­yl)[(1,2,5,6-η)-cyclo­octa-1,5-diene]rhodium(I) with tris­(2,4-di-tert-butyl­phen­yl)phosphite in toluene produces the title compound, [Rh(C(42)H(62)O(3)P)(C(8)H(12))]·C(7)H(8), by spontaneous metallation at one of the nonsubstituted phenyl ortho-C atoms of the phosphite mol­ecule. The coordination geometry at the Rh(I) ion is distorted square-planar. The toluene solvent mol­ecule is disordered over two different orientations, with site-occupation factors of 0.810 (2) and 0.190 (2). International Union of Crystallography 2012-01-31 /pmc/articles/PMC3274931/ /pubmed/22346878 http://dx.doi.org/10.1107/S1600536812002851 Text en © Selent et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Selent, Detlef
Spannenberg, Anke
Börner, Armin
{2-[Bis(2,4-di-tert-butyl­phen­oxy)phosphan­yloxy-κP]-3,5-di-tert-butyl­phenyl-κC (1)}[(1,2,5,6-η)-cyclo­octa-1,5-diene]rhodium(I) toluene monosolvate
title {2-[Bis(2,4-di-tert-butyl­phen­oxy)phosphan­yloxy-κP]-3,5-di-tert-butyl­phenyl-κC (1)}[(1,2,5,6-η)-cyclo­octa-1,5-diene]rhodium(I) toluene monosolvate
title_full {2-[Bis(2,4-di-tert-butyl­phen­oxy)phosphan­yloxy-κP]-3,5-di-tert-butyl­phenyl-κC (1)}[(1,2,5,6-η)-cyclo­octa-1,5-diene]rhodium(I) toluene monosolvate
title_fullStr {2-[Bis(2,4-di-tert-butyl­phen­oxy)phosphan­yloxy-κP]-3,5-di-tert-butyl­phenyl-κC (1)}[(1,2,5,6-η)-cyclo­octa-1,5-diene]rhodium(I) toluene monosolvate
title_full_unstemmed {2-[Bis(2,4-di-tert-butyl­phen­oxy)phosphan­yloxy-κP]-3,5-di-tert-butyl­phenyl-κC (1)}[(1,2,5,6-η)-cyclo­octa-1,5-diene]rhodium(I) toluene monosolvate
title_short {2-[Bis(2,4-di-tert-butyl­phen­oxy)phosphan­yloxy-κP]-3,5-di-tert-butyl­phenyl-κC (1)}[(1,2,5,6-η)-cyclo­octa-1,5-diene]rhodium(I) toluene monosolvate
title_sort {2-[bis(2,4-di-tert-butyl­phen­oxy)phosphan­yloxy-κp]-3,5-di-tert-butyl­phenyl-κc (1)}[(1,2,5,6-η)-cyclo­octa-1,5-diene]rhodium(i) toluene monosolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274931/
https://www.ncbi.nlm.nih.gov/pubmed/22346878
http://dx.doi.org/10.1107/S1600536812002851
work_keys_str_mv AT selentdetlef 2bis24ditertbutylphenoxyphosphanyloxykp35ditertbutylphenylkc11256ēcycloocta15dienerhodiumitoluenemonosolvate
AT spannenberganke 2bis24ditertbutylphenoxyphosphanyloxykp35ditertbutylphenylkc11256ēcycloocta15dienerhodiumitoluenemonosolvate
AT bornerarmin 2bis24ditertbutylphenoxyphosphanyloxykp35ditertbutylphenylkc11256ēcycloocta15dienerhodiumitoluenemonosolvate

Ejemplares similares