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[(4R,5R)-(2,2-Dimethyl-1,3-dioxolane-4,5-diyl)bis(diphenylmethanolato)-κ(2) O:O′]bis(N-methylmethanaminato)titanium(IV)
In the title four-coordinate complex, [Ti(C(2)H(6)N)(2)(C(31)H(28)O(4))], two symmetry-independent molecules are present in the asymmetric unit. The Ti(IV) atom displays a distorted tetrahedral geometry, with Ti—O bond lengths ranging from 1.805 (3) to 1.830 (3) Å and O—Ti—O ligand bite angles of...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2012
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274933/ https://www.ncbi.nlm.nih.gov/pubmed/22346880 http://dx.doi.org/10.1107/S1600536812002929 |
| Sumario: | In the title four-coordinate complex, [Ti(C(2)H(6)N)(2)(C(31)H(28)O(4))], two symmetry-independent molecules are present in the asymmetric unit. The Ti(IV) atom displays a distorted tetrahedral geometry, with Ti—O bond lengths ranging from 1.805 (3) to 1.830 (3) Å and O—Ti—O ligand bite angles of 100.16 (12) and 101.36 (12)°. The short Ti—N bond distances, ranging from 1.877 (4) to 1.905 (4) Å, indicate strong bonding between the Ti(IV) atom and the dimethylamide ligands. |
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