[(4R,5R)-(2,2-Dimethyl-1,3-dioxolane-4,5-di­yl)bis­(diphenyl­methano­lato)-κ(2) O:O′]bis(N-methyl­methanamin­ato)titanium(IV)

In the title four-coordinate complex, [Ti(C(2)H(6)N)(2)(C(31)H(28)O(4))], two symmetry-independent mol­ecules are present in the asymmetric unit. The Ti(IV) atom displays a distorted tetra­hedral geometry, with Ti—O bond lengths ranging from 1.805 (3) to 1.830 (3) Å and O—Ti—O ligand bite angles of...

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Detalles Bibliográficos
Autores principales: Roteta, Leslie, Tanski, Joseph M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274933/
https://www.ncbi.nlm.nih.gov/pubmed/22346880
http://dx.doi.org/10.1107/S1600536812002929
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author Roteta, Leslie
Tanski, Joseph M.
author_facet Roteta, Leslie
Tanski, Joseph M.
author_sort Roteta, Leslie
collection PubMed
description In the title four-coordinate complex, [Ti(C(2)H(6)N)(2)(C(31)H(28)O(4))], two symmetry-independent mol­ecules are present in the asymmetric unit. The Ti(IV) atom displays a distorted tetra­hedral geometry, with Ti—O bond lengths ranging from 1.805 (3) to 1.830 (3) Å and O—Ti—O ligand bite angles of 100.16 (12) and 101.36 (12)°. The short Ti—N bond distances, ranging from 1.877 (4) to 1.905 (4) Å, indicate strong bonding between the Ti(IV) atom and the dimethyl­amide ligands.
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spelling pubmed-32749332012-02-15 [(4R,5R)-(2,2-Dimethyl-1,3-dioxolane-4,5-di­yl)bis­(diphenyl­methano­lato)-κ(2) O:O′]bis(N-methyl­methanamin­ato)titanium(IV) Roteta, Leslie Tanski, Joseph M. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title four-coordinate complex, [Ti(C(2)H(6)N)(2)(C(31)H(28)O(4))], two symmetry-independent mol­ecules are present in the asymmetric unit. The Ti(IV) atom displays a distorted tetra­hedral geometry, with Ti—O bond lengths ranging from 1.805 (3) to 1.830 (3) Å and O—Ti—O ligand bite angles of 100.16 (12) and 101.36 (12)°. The short Ti—N bond distances, ranging from 1.877 (4) to 1.905 (4) Å, indicate strong bonding between the Ti(IV) atom and the dimethyl­amide ligands. International Union of Crystallography 2012-01-26 /pmc/articles/PMC3274933/ /pubmed/22346880 http://dx.doi.org/10.1107/S1600536812002929 Text en © Roteta and Tanski 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Roteta, Leslie
Tanski, Joseph M.
[(4R,5R)-(2,2-Dimethyl-1,3-dioxolane-4,5-di­yl)bis­(diphenyl­methano­lato)-κ(2) O:O′]bis(N-methyl­methanamin­ato)titanium(IV)
title [(4R,5R)-(2,2-Dimethyl-1,3-dioxolane-4,5-di­yl)bis­(diphenyl­methano­lato)-κ(2) O:O′]bis(N-methyl­methanamin­ato)titanium(IV)
title_full [(4R,5R)-(2,2-Dimethyl-1,3-dioxolane-4,5-di­yl)bis­(diphenyl­methano­lato)-κ(2) O:O′]bis(N-methyl­methanamin­ato)titanium(IV)
title_fullStr [(4R,5R)-(2,2-Dimethyl-1,3-dioxolane-4,5-di­yl)bis­(diphenyl­methano­lato)-κ(2) O:O′]bis(N-methyl­methanamin­ato)titanium(IV)
title_full_unstemmed [(4R,5R)-(2,2-Dimethyl-1,3-dioxolane-4,5-di­yl)bis­(diphenyl­methano­lato)-κ(2) O:O′]bis(N-methyl­methanamin­ato)titanium(IV)
title_short [(4R,5R)-(2,2-Dimethyl-1,3-dioxolane-4,5-di­yl)bis­(diphenyl­methano­lato)-κ(2) O:O′]bis(N-methyl­methanamin­ato)titanium(IV)
title_sort [(4r,5r)-(2,2-dimethyl-1,3-dioxolane-4,5-di­yl)bis­(diphenyl­methano­lato)-κ(2) o:o′]bis(n-methyl­methanamin­ato)titanium(iv)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274933/
https://www.ncbi.nlm.nih.gov/pubmed/22346880
http://dx.doi.org/10.1107/S1600536812002929
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AT tanskijosephm 4r5r22dimethyl13dioxolane45diylbisdiphenylmethanolatok2oobisnmethylmethanaminatotitaniumiv

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