Bis{2-[(2,4-dimethyl­phen­yl)imino­meth­yl]pyridine-κ(2) N,N′}bis­(thio­cyanato-κN)cadmium

The title compound, [Cd(NCS)(2)(C(14)H(14)N(2))(2)], features crystallographic inversion symmetry with the Cd(II) ion located on a centre of inversion. The Cd(II) ion is six-coordinated in a slightly distorted octa­hedral geometry with the thiocyanate anions in axial positions. The angle between the...

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Detalles Bibliográficos
Autores principales: Malekshahian, Mohammad, Talei Bavil Olyai, Mohamad Reza, Notash, Behrouz
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274934/
https://www.ncbi.nlm.nih.gov/pubmed/22346881
http://dx.doi.org/10.1107/S1600536812002772
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author Malekshahian, Mohammad
Talei Bavil Olyai, Mohamad Reza
Notash, Behrouz
author_facet Malekshahian, Mohammad
Talei Bavil Olyai, Mohamad Reza
Notash, Behrouz
author_sort Malekshahian, Mohammad
collection PubMed
description The title compound, [Cd(NCS)(2)(C(14)H(14)N(2))(2)], features crystallographic inversion symmetry with the Cd(II) ion located on a centre of inversion. The Cd(II) ion is six-coordinated in a slightly distorted octa­hedral geometry with the thiocyanate anions in axial positions. The angle between the benzene and pyridine rings is 69.64 (9)°. An inter­molecular C—H⋯S hydrogen bond stabilizes the crystal structure.
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spelling pubmed-32749342012-02-15 Bis{2-[(2,4-dimethyl­phen­yl)imino­meth­yl]pyridine-κ(2) N,N′}bis­(thio­cyanato-κN)cadmium Malekshahian, Mohammad Talei Bavil Olyai, Mohamad Reza Notash, Behrouz Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Cd(NCS)(2)(C(14)H(14)N(2))(2)], features crystallographic inversion symmetry with the Cd(II) ion located on a centre of inversion. The Cd(II) ion is six-coordinated in a slightly distorted octa­hedral geometry with the thiocyanate anions in axial positions. The angle between the benzene and pyridine rings is 69.64 (9)°. An inter­molecular C—H⋯S hydrogen bond stabilizes the crystal structure. International Union of Crystallography 2012-01-31 /pmc/articles/PMC3274934/ /pubmed/22346881 http://dx.doi.org/10.1107/S1600536812002772 Text en © Malekshahian et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Malekshahian, Mohammad
Talei Bavil Olyai, Mohamad Reza
Notash, Behrouz
Bis{2-[(2,4-dimethyl­phen­yl)imino­meth­yl]pyridine-κ(2) N,N′}bis­(thio­cyanato-κN)cadmium
title Bis{2-[(2,4-dimethyl­phen­yl)imino­meth­yl]pyridine-κ(2) N,N′}bis­(thio­cyanato-κN)cadmium
title_full Bis{2-[(2,4-dimethyl­phen­yl)imino­meth­yl]pyridine-κ(2) N,N′}bis­(thio­cyanato-κN)cadmium
title_fullStr Bis{2-[(2,4-dimethyl­phen­yl)imino­meth­yl]pyridine-κ(2) N,N′}bis­(thio­cyanato-κN)cadmium
title_full_unstemmed Bis{2-[(2,4-dimethyl­phen­yl)imino­meth­yl]pyridine-κ(2) N,N′}bis­(thio­cyanato-κN)cadmium
title_short Bis{2-[(2,4-dimethyl­phen­yl)imino­meth­yl]pyridine-κ(2) N,N′}bis­(thio­cyanato-κN)cadmium
title_sort bis{2-[(2,4-dimethyl­phen­yl)imino­meth­yl]pyridine-κ(2) n,n′}bis­(thio­cyanato-κn)cadmium
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274934/
https://www.ncbi.nlm.nih.gov/pubmed/22346881
http://dx.doi.org/10.1107/S1600536812002772
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AT notashbehrouz bis224dimethylphenyliminomethylpyridinek2nnbisthiocyanatokncadmium

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