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Bis(η(6)-naphthalene)­molybdenum(0)

The title compound, [Mo(C(10)H(8))(2)], was prepared from the naphthalene radical anion and MoCl(4)(thf)(2) (thf is tetra­hydro­furan). In the crystal, the mol­ecule is located on an inversion center. The Mo atom is equally disordered over two positions; the range of Mo—C distances is 2.2244 (19)–2....

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Detalles Bibliográficos
Autores principales: Minyaev, Mikhail E., Ellis, John E., Wolf, William J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274935/
https://www.ncbi.nlm.nih.gov/pubmed/22346882
http://dx.doi.org/10.1107/S1600536812002504
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author Minyaev, Mikhail E.
Ellis, John E.
Wolf, William J.
author_facet Minyaev, Mikhail E.
Ellis, John E.
Wolf, William J.
author_sort Minyaev, Mikhail E.
collection PubMed
description The title compound, [Mo(C(10)H(8))(2)], was prepared from the naphthalene radical anion and MoCl(4)(thf)(2) (thf is tetra­hydro­furan). In the crystal, the mol­ecule is located on an inversion center. The Mo atom is equally disordered over two positions; the range of Mo—C distances is 2.2244 (19)–2.3400 (17) Å for both components of the disorder.
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spelling pubmed-32749352012-02-15 Bis(η(6)-naphthalene)­molybdenum(0) Minyaev, Mikhail E. Ellis, John E. Wolf, William J. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Mo(C(10)H(8))(2)], was prepared from the naphthalene radical anion and MoCl(4)(thf)(2) (thf is tetra­hydro­furan). In the crystal, the mol­ecule is located on an inversion center. The Mo atom is equally disordered over two positions; the range of Mo—C distances is 2.2244 (19)–2.3400 (17) Å for both components of the disorder. International Union of Crystallography 2012-01-31 /pmc/articles/PMC3274935/ /pubmed/22346882 http://dx.doi.org/10.1107/S1600536812002504 Text en © Minyaev et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Minyaev, Mikhail E.
Ellis, John E.
Wolf, William J.
Bis(η(6)-naphthalene)­molybdenum(0)
title Bis(η(6)-naphthalene)­molybdenum(0)
title_full Bis(η(6)-naphthalene)­molybdenum(0)
title_fullStr Bis(η(6)-naphthalene)­molybdenum(0)
title_full_unstemmed Bis(η(6)-naphthalene)­molybdenum(0)
title_short Bis(η(6)-naphthalene)­molybdenum(0)
title_sort bis(η(6)-naphthalene)­molybdenum(0)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274935/
https://www.ncbi.nlm.nih.gov/pubmed/22346882
http://dx.doi.org/10.1107/S1600536812002504
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AT wolfwilliamj bisē6naphthalenemolybdenum0