{4-Bromo-2-[(5-chloro-2-oxidophen­yl)imino­methyl]­phenolato-κ(3) O,N,O′}(methanol-κO)(methano­lato-κO)­oxidovanadium(V)

The title Schiff base complex, [V(C(13)H(7)BrClNO(2))(CH(3)O)O(CH(3)OH)], features a vanadyl group, a tridentate Schiff base ligand, and coordinated methanol and methano­late ligands. The NO(5) donor set is based on a distorted octa­hedron. Helical supra­molecular chains along [010] are found in the...

Descripción completa

Detalles Bibliográficos
Autores principales: Shahverdizadeh, Gholam Hossein, Ng, Seik Weng, Tiekink, Edward R. T., Mirtamizdoust, Babak
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274936/
https://www.ncbi.nlm.nih.gov/pubmed/22346883
http://dx.doi.org/10.1107/S160053681200311X
_version_ 1782223139573334016
author Shahverdizadeh, Gholam Hossein
Ng, Seik Weng
Tiekink, Edward R. T.
Mirtamizdoust, Babak
author_facet Shahverdizadeh, Gholam Hossein
Ng, Seik Weng
Tiekink, Edward R. T.
Mirtamizdoust, Babak
author_sort Shahverdizadeh, Gholam Hossein
collection PubMed
description The title Schiff base complex, [V(C(13)H(7)BrClNO(2))(CH(3)O)O(CH(3)OH)], features a vanadyl group, a tridentate Schiff base ligand, and coordinated methanol and methano­late ligands. The NO(5) donor set is based on a distorted octa­hedron. Helical supra­molecular chains along [010] are found in the crystal structure mediated by O—H⋯O hydrogen bonds formed between the coordinating methanol mol­ecule and the phenolate O atom of the chloro­benzene residue.
format Online
Article
Text
id pubmed-3274936
institution National Center for Biotechnology Information
language English
publishDate 2012
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-32749362012-02-15 {4-Bromo-2-[(5-chloro-2-oxidophen­yl)imino­methyl]­phenolato-κ(3) O,N,O′}(methanol-κO)(methano­lato-κO)­oxidovanadium(V) Shahverdizadeh, Gholam Hossein Ng, Seik Weng Tiekink, Edward R. T. Mirtamizdoust, Babak Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title Schiff base complex, [V(C(13)H(7)BrClNO(2))(CH(3)O)O(CH(3)OH)], features a vanadyl group, a tridentate Schiff base ligand, and coordinated methanol and methano­late ligands. The NO(5) donor set is based on a distorted octa­hedron. Helical supra­molecular chains along [010] are found in the crystal structure mediated by O—H⋯O hydrogen bonds formed between the coordinating methanol mol­ecule and the phenolate O atom of the chloro­benzene residue. International Union of Crystallography 2012-01-31 /pmc/articles/PMC3274936/ /pubmed/22346883 http://dx.doi.org/10.1107/S160053681200311X Text en © Shahverdizadeh et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Shahverdizadeh, Gholam Hossein
Ng, Seik Weng
Tiekink, Edward R. T.
Mirtamizdoust, Babak
{4-Bromo-2-[(5-chloro-2-oxidophen­yl)imino­methyl]­phenolato-κ(3) O,N,O′}(methanol-κO)(methano­lato-κO)­oxidovanadium(V)
title {4-Bromo-2-[(5-chloro-2-oxidophen­yl)imino­methyl]­phenolato-κ(3) O,N,O′}(methanol-κO)(methano­lato-κO)­oxidovanadium(V)
title_full {4-Bromo-2-[(5-chloro-2-oxidophen­yl)imino­methyl]­phenolato-κ(3) O,N,O′}(methanol-κO)(methano­lato-κO)­oxidovanadium(V)
title_fullStr {4-Bromo-2-[(5-chloro-2-oxidophen­yl)imino­methyl]­phenolato-κ(3) O,N,O′}(methanol-κO)(methano­lato-κO)­oxidovanadium(V)
title_full_unstemmed {4-Bromo-2-[(5-chloro-2-oxidophen­yl)imino­methyl]­phenolato-κ(3) O,N,O′}(methanol-κO)(methano­lato-κO)­oxidovanadium(V)
title_short {4-Bromo-2-[(5-chloro-2-oxidophen­yl)imino­methyl]­phenolato-κ(3) O,N,O′}(methanol-κO)(methano­lato-κO)­oxidovanadium(V)
title_sort {4-bromo-2-[(5-chloro-2-oxidophen­yl)imino­methyl]­phenolato-κ(3) o,n,o′}(methanol-κo)(methano­lato-κo)­oxidovanadium(v)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274936/
https://www.ncbi.nlm.nih.gov/pubmed/22346883
http://dx.doi.org/10.1107/S160053681200311X
work_keys_str_mv AT shahverdizadehgholamhossein 4bromo25chloro2oxidophenyliminomethylphenolatok3onomethanolkomethanolatokooxidovanadiumv
AT ngseikweng 4bromo25chloro2oxidophenyliminomethylphenolatok3onomethanolkomethanolatokooxidovanadiumv
AT tiekinkedwardrt 4bromo25chloro2oxidophenyliminomethylphenolatok3onomethanolkomethanolatokooxidovanadiumv
AT mirtamizdoustbabak 4bromo25chloro2oxidophenyliminomethylphenolatok3onomethanolkomethanolatokooxidovanadiumv

Ejemplares similares