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Chlorido(1,2-dimethyl-1H-imidazole-κN (3)){2-[(diphenoxyphosphanyl)oxy]phenyl-κ(2) C (1),P}palladium(II)
The Pd atom in the title compound, [Pd(C(18)H(14)O(3)P)Cl(C(5)H(8)N(2))], adopts a slightly distorted square-planar coordination geometry, with the metallated carbon positioned trans to the Cl atom. The crystal structure is stabilized by several weak C—H⋯O and C—H⋯Cl hydrogen-bond interactions. One...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2012
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274940/ https://www.ncbi.nlm.nih.gov/pubmed/22346887 http://dx.doi.org/10.1107/S1600536812003431 |
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| author | Błaszczyk, Izabela Trzeciak, Anna M. Gniewek, Andrzej |
| author_facet | Błaszczyk, Izabela Trzeciak, Anna M. Gniewek, Andrzej |
| author_sort | Błaszczyk, Izabela |
| collection | PubMed |
| description | The Pd atom in the title compound, [Pd(C(18)H(14)O(3)P)Cl(C(5)H(8)N(2))], adopts a slightly distorted square-planar coordination geometry, with the metallated carbon positioned trans to the Cl atom. The crystal structure is stabilized by several weak C—H⋯O and C—H⋯Cl hydrogen-bond interactions. One of the phenyl rings is disordered over two almost equally occupied sites. |
| format | Online Article Text |
| id | pubmed-3274940 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2012 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-32749402012-02-15 Chlorido(1,2-dimethyl-1H-imidazole-κN (3)){2-[(diphenoxyphosphanyl)oxy]phenyl-κ(2) C (1),P}palladium(II) Błaszczyk, Izabela Trzeciak, Anna M. Gniewek, Andrzej Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Pd atom in the title compound, [Pd(C(18)H(14)O(3)P)Cl(C(5)H(8)N(2))], adopts a slightly distorted square-planar coordination geometry, with the metallated carbon positioned trans to the Cl atom. The crystal structure is stabilized by several weak C—H⋯O and C—H⋯Cl hydrogen-bond interactions. One of the phenyl rings is disordered over two almost equally occupied sites. International Union of Crystallography 2012-01-31 /pmc/articles/PMC3274940/ /pubmed/22346887 http://dx.doi.org/10.1107/S1600536812003431 Text en © Błaszczyk et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Błaszczyk, Izabela Trzeciak, Anna M. Gniewek, Andrzej Chlorido(1,2-dimethyl-1H-imidazole-κN (3)){2-[(diphenoxyphosphanyl)oxy]phenyl-κ(2) C (1),P}palladium(II) |
| title | Chlorido(1,2-dimethyl-1H-imidazole-κN
(3)){2-[(diphenoxyphosphanyl)oxy]phenyl-κ(2)
C
(1),P}palladium(II) |
| title_full | Chlorido(1,2-dimethyl-1H-imidazole-κN
(3)){2-[(diphenoxyphosphanyl)oxy]phenyl-κ(2)
C
(1),P}palladium(II) |
| title_fullStr | Chlorido(1,2-dimethyl-1H-imidazole-κN
(3)){2-[(diphenoxyphosphanyl)oxy]phenyl-κ(2)
C
(1),P}palladium(II) |
| title_full_unstemmed | Chlorido(1,2-dimethyl-1H-imidazole-κN
(3)){2-[(diphenoxyphosphanyl)oxy]phenyl-κ(2)
C
(1),P}palladium(II) |
| title_short | Chlorido(1,2-dimethyl-1H-imidazole-κN
(3)){2-[(diphenoxyphosphanyl)oxy]phenyl-κ(2)
C
(1),P}palladium(II) |
| title_sort | chlorido(1,2-dimethyl-1h-imidazole-κn
(3)){2-[(diphenoxyphosphanyl)oxy]phenyl-κ(2)
c
(1),p}palladium(ii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274940/ https://www.ncbi.nlm.nih.gov/pubmed/22346887 http://dx.doi.org/10.1107/S1600536812003431 |
| work_keys_str_mv | AT błaszczykizabela chlorido12dimethyl1himidazolekn32diphenoxyphosphanyloxyphenylk2c1ppalladiumii AT trzeciakannam chlorido12dimethyl1himidazolekn32diphenoxyphosphanyloxyphenylk2c1ppalladiumii AT gniewekandrzej chlorido12dimethyl1himidazolekn32diphenoxyphosphanyloxyphenylk2c1ppalladiumii |