1-Ferrocenyl-3-(4-methyl­anilino)propan-1-one

In the title ferrocene derivative, [Fe(C(5)H(5))(C(15)H(16)NO)], the dihedral angle between the best planes of the benzene and the substituted cyclo­penta­dienyl ring is 83.4 (1)°. The presence of a methyl substituent in the para position of the aniline group does not alter the crystal packing compa...

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Autores principales: Leka, Zorica, Novaković, Sladjana B., Stevanović, Dragana, Bogdanović, Goran A., Vukićević, Rastko D.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274942/
https://www.ncbi.nlm.nih.gov/pubmed/22346889
http://dx.doi.org/10.1107/S1600536812003509
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author Leka, Zorica
Novaković, Sladjana B.
Stevanović, Dragana
Bogdanović, Goran A.
Vukićević, Rastko D.
author_facet Leka, Zorica
Novaković, Sladjana B.
Stevanović, Dragana
Bogdanović, Goran A.
Vukićević, Rastko D.
author_sort Leka, Zorica
collection PubMed
description In the title ferrocene derivative, [Fe(C(5)H(5))(C(15)H(16)NO)], the dihedral angle between the best planes of the benzene and the substituted cyclo­penta­dienyl ring is 83.4 (1)°. The presence of a methyl substituent in the para position of the aniline group does not alter the crystal packing compared to that of 3-anilino-1-ferrocenylpropan-1-one [Leka et al. (2012 ▶). Acta Cryst. E68, m229]. The molecules are connected into centro­symmetric dimers via N—H⋯O hydrogen bonds. In addition, C—H⋯O and C—H⋯N contacts stabilize the crystal packing.
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spelling pubmed-32749422012-02-15 1-Ferrocenyl-3-(4-methyl­anilino)propan-1-one Leka, Zorica Novaković, Sladjana B. Stevanović, Dragana Bogdanović, Goran A. Vukićević, Rastko D. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title ferrocene derivative, [Fe(C(5)H(5))(C(15)H(16)NO)], the dihedral angle between the best planes of the benzene and the substituted cyclo­penta­dienyl ring is 83.4 (1)°. The presence of a methyl substituent in the para position of the aniline group does not alter the crystal packing compared to that of 3-anilino-1-ferrocenylpropan-1-one [Leka et al. (2012 ▶). Acta Cryst. E68, m229]. The molecules are connected into centro­symmetric dimers via N—H⋯O hydrogen bonds. In addition, C—H⋯O and C—H⋯N contacts stabilize the crystal packing. International Union of Crystallography 2012-01-31 /pmc/articles/PMC3274942/ /pubmed/22346889 http://dx.doi.org/10.1107/S1600536812003509 Text en © Leka et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Leka, Zorica
Novaković, Sladjana B.
Stevanović, Dragana
Bogdanović, Goran A.
Vukićević, Rastko D.
1-Ferrocenyl-3-(4-methyl­anilino)propan-1-one
title 1-Ferrocenyl-3-(4-methyl­anilino)propan-1-one
title_full 1-Ferrocenyl-3-(4-methyl­anilino)propan-1-one
title_fullStr 1-Ferrocenyl-3-(4-methyl­anilino)propan-1-one
title_full_unstemmed 1-Ferrocenyl-3-(4-methyl­anilino)propan-1-one
title_short 1-Ferrocenyl-3-(4-methyl­anilino)propan-1-one
title_sort 1-ferrocenyl-3-(4-methyl­anilino)propan-1-one
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274942/
https://www.ncbi.nlm.nih.gov/pubmed/22346889
http://dx.doi.org/10.1107/S1600536812003509
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AT bogdanovicgorana 1ferrocenyl34methylanilinopropan1one
AT vukicevicrastkod 1ferrocenyl34methylanilinopropan1one

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