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1-Ferrocenyl-3-(3-fluoroanilino)propan-1-one
The title ferrocene derivative, [Fe(C(5)H(5))(C(14)H(13)FNO)], crystallizes in the same space group with similar unit-cell parameters as the derivatives 3-anilino-1-ferrocenylpropan-1-one [Leka et al. (2012 ▶). Acta Cryst. E68, m229] and 1-ferrocenyl-3-(4-methylanilino)propan-1-one [Leka et al. (20...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2012
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274943/ https://www.ncbi.nlm.nih.gov/pubmed/22346890 http://dx.doi.org/10.1107/S1600536812003510 |
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| author | Leka, Zorica Novaković, Sladjana B. Pejović, Anka Bogdanović, Goran A. Vukićević, Rastko D. |
| author_facet | Leka, Zorica Novaković, Sladjana B. Pejović, Anka Bogdanović, Goran A. Vukićević, Rastko D. |
| author_sort | Leka, Zorica |
| collection | PubMed |
| description | The title ferrocene derivative, [Fe(C(5)H(5))(C(14)H(13)FNO)], crystallizes in the same space group with similar unit-cell parameters as the derivatives 3-anilino-1-ferrocenylpropan-1-one [Leka et al. (2012 ▶). Acta Cryst. E68, m229] and 1-ferrocenyl-3-(4-methylanilino)propan-1-one [Leka et al. (2012 ▶). Acta Cryst. E68, m230]. The dihedral angle between the best planes of the benzene ring and the substituted cyclopentadienyl ring is 83.4 (1)°. The presence of the electronegative fluoro substituent in the meta position of the aniline group does not alter the crystal packing compared to the other two derivatives. The molecules are connected into centrosymmetric dimers via N—H⋯O hydrogen bonds. In addition, C—H⋯O and C—H⋯N contacts stabilize the crystal packing. |
| format | Online Article Text |
| id | pubmed-3274943 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2012 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-32749432012-02-15 1-Ferrocenyl-3-(3-fluoroanilino)propan-1-one Leka, Zorica Novaković, Sladjana B. Pejović, Anka Bogdanović, Goran A. Vukićević, Rastko D. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title ferrocene derivative, [Fe(C(5)H(5))(C(14)H(13)FNO)], crystallizes in the same space group with similar unit-cell parameters as the derivatives 3-anilino-1-ferrocenylpropan-1-one [Leka et al. (2012 ▶). Acta Cryst. E68, m229] and 1-ferrocenyl-3-(4-methylanilino)propan-1-one [Leka et al. (2012 ▶). Acta Cryst. E68, m230]. The dihedral angle between the best planes of the benzene ring and the substituted cyclopentadienyl ring is 83.4 (1)°. The presence of the electronegative fluoro substituent in the meta position of the aniline group does not alter the crystal packing compared to the other two derivatives. The molecules are connected into centrosymmetric dimers via N—H⋯O hydrogen bonds. In addition, C—H⋯O and C—H⋯N contacts stabilize the crystal packing. International Union of Crystallography 2012-01-31 /pmc/articles/PMC3274943/ /pubmed/22346890 http://dx.doi.org/10.1107/S1600536812003510 Text en © Leka et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Leka, Zorica Novaković, Sladjana B. Pejović, Anka Bogdanović, Goran A. Vukićević, Rastko D. 1-Ferrocenyl-3-(3-fluoroanilino)propan-1-one |
| title | 1-Ferrocenyl-3-(3-fluoroanilino)propan-1-one |
| title_full | 1-Ferrocenyl-3-(3-fluoroanilino)propan-1-one |
| title_fullStr | 1-Ferrocenyl-3-(3-fluoroanilino)propan-1-one |
| title_full_unstemmed | 1-Ferrocenyl-3-(3-fluoroanilino)propan-1-one |
| title_short | 1-Ferrocenyl-3-(3-fluoroanilino)propan-1-one |
| title_sort | 1-ferrocenyl-3-(3-fluoroanilino)propan-1-one |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274943/ https://www.ncbi.nlm.nih.gov/pubmed/22346890 http://dx.doi.org/10.1107/S1600536812003510 |
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