Cargando…
Space group revsion of the triclinic polymorph of salicylaldehyde azine
The structure of the title compound, C(14)H(12)N(2)O(2) {systematic name: 2,2′-[hydrazinediylidenebis(methanylylidene)]diphenol}, has already been determined in the triclinic space group P [Image: see text] with Z = 4 [El-Medani, Aboaly, Abdalla & Ramadan (2004 ▶). Spectrosc. Lett. 37, 619–632...
Autores principales: | , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274948/ https://www.ncbi.nlm.nih.gov/pubmed/22346901 http://dx.doi.org/10.1107/S160053681105478X |
Sumario: | The structure of the title compound, C(14)H(12)N(2)O(2) {systematic name: 2,2′-[hydrazinediylidenebis(methanylylidene)]diphenol}, has already been determined in the triclinic space group P [Image: see text] with Z = 4 [El-Medani, Aboaly, Abdalla & Ramadan (2004 ▶). Spectrosc. Lett. 37, 619–632]. However, the correct space group should be P2(1)/c with Z = 4. This structure is a new polymorph of the already known monoclinic polymorph of salicyladehyde azine, which crystallizes in space group P2(1)/n with Z = 2. The benzene rings form a dihedral angle of 46.12 (9)°. Two intramolucular O—H⋯N hydrogen bonds occur. |
---|