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N,N′-Dibenzyl-N′′-(2,4-difluorobenzoyl)-N,N′-dimethylphosphoric triamide
In the title molecule, C(23)H(24)F(2)N(3)O(2)P, the P atom is in a distorted tetrahedral P(=O)(N)(N)(2) environment, with the bond angles around the P atom in the range 106.78 (11)–114.10 (13)°. The phosphoryl and carbonyl groups, which are separated by an N atom, adopt an anti orientation relativ...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274968/ https://www.ncbi.nlm.nih.gov/pubmed/22346913 http://dx.doi.org/10.1107/S1600536811055115 |
Sumario: | In the title molecule, C(23)H(24)F(2)N(3)O(2)P, the P atom is in a distorted tetrahedral P(=O)(N)(N)(2) environment, with the bond angles around the P atom in the range 106.78 (11)–114.10 (13)°. The phosphoryl and carbonyl groups, which are separated by an N atom, adopt an anti orientation relative to each other. In the C(=O)NHP(=O) fragment, the P—N bond is longer [1.683 (2) Å] and the O—P—N angle is smaller [106.78 (11)°] than the other P—N bonds [1.613 (2) and 1.632 (2) Å] and O—P—N bond angles [114.10 (13) and 110.83 (12)°], respectively. The N atoms have sp (2) character. In the crystal, pairs of P=O⋯H—N hydrogen bonds form inversion dimers with R (2) (2)(8) ring motifs. |
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