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N,N′-Dibenzyl-N′′-(2,4-difluoro­benzo­yl)-N,N′-dimethyl­phospho­ric triamide

In the title mol­ecule, C(23)H(24)F(2)N(3)O(2)P, the P atom is in a distorted tetra­hedral P(=O)(N)(N)(2) environment, with the bond angles around the P atom in the range 106.78 (11)–114.10 (13)°. The phosphoryl and carbonyl groups, which are separated by an N atom, adopt an anti orientation relativ...

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Autores principales: Pourayoubi, Mehrdad, Shoghpour, Samad, Torre-Fernández, Laura, García-Granda, Santiago
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274968/
https://www.ncbi.nlm.nih.gov/pubmed/22346913
http://dx.doi.org/10.1107/S1600536811055115
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author Pourayoubi, Mehrdad
Shoghpour, Samad
Torre-Fernández, Laura
García-Granda, Santiago
author_facet Pourayoubi, Mehrdad
Shoghpour, Samad
Torre-Fernández, Laura
García-Granda, Santiago
author_sort Pourayoubi, Mehrdad
collection PubMed
description In the title mol­ecule, C(23)H(24)F(2)N(3)O(2)P, the P atom is in a distorted tetra­hedral P(=O)(N)(N)(2) environment, with the bond angles around the P atom in the range 106.78 (11)–114.10 (13)°. The phosphoryl and carbonyl groups, which are separated by an N atom, adopt an anti orientation relative to each other. In the C(=O)NHP(=O) fragment, the P—N bond is longer [1.683 (2) Å] and the O—P—N angle is smaller [106.78 (11)°] than the other P—N bonds [1.613 (2) and 1.632 (2) Å] and O—P—N bond angles [114.10 (13) and 110.83 (12)°], respectively. The N atoms have sp (2) character. In the crystal, pairs of P=O⋯H—N hydrogen bonds form inversion dimers with R (2) (2)(8) ring motifs.
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spelling pubmed-32749682012-02-15 N,N′-Dibenzyl-N′′-(2,4-difluoro­benzo­yl)-N,N′-dimethyl­phospho­ric triamide Pourayoubi, Mehrdad Shoghpour, Samad Torre-Fernández, Laura García-Granda, Santiago Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title mol­ecule, C(23)H(24)F(2)N(3)O(2)P, the P atom is in a distorted tetra­hedral P(=O)(N)(N)(2) environment, with the bond angles around the P atom in the range 106.78 (11)–114.10 (13)°. The phosphoryl and carbonyl groups, which are separated by an N atom, adopt an anti orientation relative to each other. In the C(=O)NHP(=O) fragment, the P—N bond is longer [1.683 (2) Å] and the O—P—N angle is smaller [106.78 (11)°] than the other P—N bonds [1.613 (2) and 1.632 (2) Å] and O—P—N bond angles [114.10 (13) and 110.83 (12)°], respectively. The N atoms have sp (2) character. In the crystal, pairs of P=O⋯H—N hydrogen bonds form inversion dimers with R (2) (2)(8) ring motifs. International Union of Crystallography 2012-01-07 /pmc/articles/PMC3274968/ /pubmed/22346913 http://dx.doi.org/10.1107/S1600536811055115 Text en © Pourayoubi et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Pourayoubi, Mehrdad
Shoghpour, Samad
Torre-Fernández, Laura
García-Granda, Santiago
N,N′-Dibenzyl-N′′-(2,4-difluoro­benzo­yl)-N,N′-dimethyl­phospho­ric triamide
title N,N′-Dibenzyl-N′′-(2,4-difluoro­benzo­yl)-N,N′-dimethyl­phospho­ric triamide
title_full N,N′-Dibenzyl-N′′-(2,4-difluoro­benzo­yl)-N,N′-dimethyl­phospho­ric triamide
title_fullStr N,N′-Dibenzyl-N′′-(2,4-difluoro­benzo­yl)-N,N′-dimethyl­phospho­ric triamide
title_full_unstemmed N,N′-Dibenzyl-N′′-(2,4-difluoro­benzo­yl)-N,N′-dimethyl­phospho­ric triamide
title_short N,N′-Dibenzyl-N′′-(2,4-difluoro­benzo­yl)-N,N′-dimethyl­phospho­ric triamide
title_sort n,n′-dibenzyl-n′′-(2,4-difluoro­benzo­yl)-n,n′-dimethyl­phospho­ric triamide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274968/
https://www.ncbi.nlm.nih.gov/pubmed/22346913
http://dx.doi.org/10.1107/S1600536811055115
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