1-(6-Methyl-3-phenyl-2-sulfanyl­idene-1,2,3,4-tetra­hydro­pyrimidin-5-yl)ethanone

In the title compound, C(13)H(14)N(2)OS, four C atoms of the phenyl ring are disordered over two sets of sites in a 0.60 (3):0.40 (3) ratio. The heterocyclic ring is essentially planar (r.m.s. deviation = 0.017 Å) and forms dihedral angles of 82.0 (2) and 79.3 (3)°, respectively, with the major and...

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Autores principales: Garibov, Emin N., Gojayeva, Sevinj S., Allahverdiyev, Mirze A., Gurbanov, Atash V. Gurbanov, Brito, Iván
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274973/
https://www.ncbi.nlm.nih.gov/pubmed/22346918
http://dx.doi.org/10.1107/S1600536811055309
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author Garibov, Emin N.
Gojayeva, Sevinj S.
Allahverdiyev, Mirze A.
Gurbanov, Atash V. Gurbanov
Brito, Iván
author_facet Garibov, Emin N.
Gojayeva, Sevinj S.
Allahverdiyev, Mirze A.
Gurbanov, Atash V. Gurbanov
Brito, Iván
author_sort Garibov, Emin N.
collection PubMed
description In the title compound, C(13)H(14)N(2)OS, four C atoms of the phenyl ring are disordered over two sets of sites in a 0.60 (3):0.40 (3) ratio. The heterocyclic ring is essentially planar (r.m.s. deviation = 0.017 Å) and forms dihedral angles of 82.0 (2) and 79.3 (3)°, respectively, with the major and minor occupancy components of the phenyl ring. The crystal packing features N—H⋯O hydrogen bonds, which link the mol­ecules into C(6) chains running parallel to the b axis.
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spelling pubmed-32749732012-02-15 1-(6-Methyl-3-phenyl-2-sulfanyl­idene-1,2,3,4-tetra­hydro­pyrimidin-5-yl)ethanone Garibov, Emin N. Gojayeva, Sevinj S. Allahverdiyev, Mirze A. Gurbanov, Atash V. Gurbanov Brito, Iván Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(13)H(14)N(2)OS, four C atoms of the phenyl ring are disordered over two sets of sites in a 0.60 (3):0.40 (3) ratio. The heterocyclic ring is essentially planar (r.m.s. deviation = 0.017 Å) and forms dihedral angles of 82.0 (2) and 79.3 (3)°, respectively, with the major and minor occupancy components of the phenyl ring. The crystal packing features N—H⋯O hydrogen bonds, which link the mol­ecules into C(6) chains running parallel to the b axis. International Union of Crystallography 2012-01-07 /pmc/articles/PMC3274973/ /pubmed/22346918 http://dx.doi.org/10.1107/S1600536811055309 Text en © Garibov et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Garibov, Emin N.
Gojayeva, Sevinj S.
Allahverdiyev, Mirze A.
Gurbanov, Atash V. Gurbanov
Brito, Iván
1-(6-Methyl-3-phenyl-2-sulfanyl­idene-1,2,3,4-tetra­hydro­pyrimidin-5-yl)ethanone
title 1-(6-Methyl-3-phenyl-2-sulfanyl­idene-1,2,3,4-tetra­hydro­pyrimidin-5-yl)ethanone
title_full 1-(6-Methyl-3-phenyl-2-sulfanyl­idene-1,2,3,4-tetra­hydro­pyrimidin-5-yl)ethanone
title_fullStr 1-(6-Methyl-3-phenyl-2-sulfanyl­idene-1,2,3,4-tetra­hydro­pyrimidin-5-yl)ethanone
title_full_unstemmed 1-(6-Methyl-3-phenyl-2-sulfanyl­idene-1,2,3,4-tetra­hydro­pyrimidin-5-yl)ethanone
title_short 1-(6-Methyl-3-phenyl-2-sulfanyl­idene-1,2,3,4-tetra­hydro­pyrimidin-5-yl)ethanone
title_sort 1-(6-methyl-3-phenyl-2-sulfanyl­idene-1,2,3,4-tetra­hydro­pyrimidin-5-yl)ethanone
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274973/
https://www.ncbi.nlm.nih.gov/pubmed/22346918
http://dx.doi.org/10.1107/S1600536811055309
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