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2-{[(4-{[(2-Hydroxyphenyl)(phenyl)methylidene]amino}butyl)imino](phenyl)methyl}phenol
The asymmetric unit of the title compound, C(30)H(28)N(2)O(2), comprises half of a potential tetradentate Schiff base ligand; an inversion centre is situtated at the center of the butanediamine spacer. The central methylene segment of the diamine spacer is disordered over two positions with a ref...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274985/ https://www.ncbi.nlm.nih.gov/pubmed/22346930 http://dx.doi.org/10.1107/S1600536811055905 |
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author | Jamshidvand, Arezoo Kia, Reza Kargar, Hadi Tahir, Muhammad Nawaz |
author_facet | Jamshidvand, Arezoo Kia, Reza Kargar, Hadi Tahir, Muhammad Nawaz |
author_sort | Jamshidvand, Arezoo |
collection | PubMed |
description | The asymmetric unit of the title compound, C(30)H(28)N(2)O(2), comprises half of a potential tetradentate Schiff base ligand; an inversion centre is situtated at the center of the butanediamine spacer. The central methylene segment of the diamine spacer is disordered over two positions with a refined site-occupancy ratio of 0.651 (7):0.349 (7). The phenyl ring and the hydroxy-substituted benzene ring are almost perpendicular to each other, with a dihedral angle of 87.90 (8) Å. Intramolecular O—H⋯N hydrogen bonds make S(6) ring motifs. |
format | Online Article Text |
id | pubmed-3274985 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32749852012-02-15 2-{[(4-{[(2-Hydroxyphenyl)(phenyl)methylidene]amino}butyl)imino](phenyl)methyl}phenol Jamshidvand, Arezoo Kia, Reza Kargar, Hadi Tahir, Muhammad Nawaz Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title compound, C(30)H(28)N(2)O(2), comprises half of a potential tetradentate Schiff base ligand; an inversion centre is situtated at the center of the butanediamine spacer. The central methylene segment of the diamine spacer is disordered over two positions with a refined site-occupancy ratio of 0.651 (7):0.349 (7). The phenyl ring and the hydroxy-substituted benzene ring are almost perpendicular to each other, with a dihedral angle of 87.90 (8) Å. Intramolecular O—H⋯N hydrogen bonds make S(6) ring motifs. International Union of Crystallography 2012-01-07 /pmc/articles/PMC3274985/ /pubmed/22346930 http://dx.doi.org/10.1107/S1600536811055905 Text en © Jamshidvand et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Jamshidvand, Arezoo Kia, Reza Kargar, Hadi Tahir, Muhammad Nawaz 2-{[(4-{[(2-Hydroxyphenyl)(phenyl)methylidene]amino}butyl)imino](phenyl)methyl}phenol |
title | 2-{[(4-{[(2-Hydroxyphenyl)(phenyl)methylidene]amino}butyl)imino](phenyl)methyl}phenol |
title_full | 2-{[(4-{[(2-Hydroxyphenyl)(phenyl)methylidene]amino}butyl)imino](phenyl)methyl}phenol |
title_fullStr | 2-{[(4-{[(2-Hydroxyphenyl)(phenyl)methylidene]amino}butyl)imino](phenyl)methyl}phenol |
title_full_unstemmed | 2-{[(4-{[(2-Hydroxyphenyl)(phenyl)methylidene]amino}butyl)imino](phenyl)methyl}phenol |
title_short | 2-{[(4-{[(2-Hydroxyphenyl)(phenyl)methylidene]amino}butyl)imino](phenyl)methyl}phenol |
title_sort | 2-{[(4-{[(2-hydroxyphenyl)(phenyl)methylidene]amino}butyl)imino](phenyl)methyl}phenol |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274985/ https://www.ncbi.nlm.nih.gov/pubmed/22346930 http://dx.doi.org/10.1107/S1600536811055905 |
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