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2-[(5-Chloro-2-oxidobenzylidene)azaniumyl]-2-methylpropane-1,3-diol
The title compound, C(11)H(14)ClNO(3), was prepared by the condensation of equimolar quantities of 5-chlorosalicylaldehyde and 2-amino-2-methylpropane-1,3-diol in methanol. In the crystal, it exists in the zwitterionic form, with nominal proton transfer from the phenol group to the imine N atom....
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274988/ https://www.ncbi.nlm.nih.gov/pubmed/22346933 http://dx.doi.org/10.1107/S1600536811055784 |
Sumario: | The title compound, C(11)H(14)ClNO(3), was prepared by the condensation of equimolar quantities of 5-chlorosalicylaldehyde and 2-amino-2-methylpropane-1,3-diol in methanol. In the crystal, it exists in the zwitterionic form, with nominal proton transfer from the phenol group to the imine N atom. This results in the formation of an intramolecular N—H⋯O hydrogen bond, which generates an S(6) ring. Intermolecular O—H⋯O hydrogen bonds arise from the hydroxy groups, forming (001) sheets. |
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