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2-[(5-Chloro-2-oxidobenzyl­idene)aza­nium­yl]-2-methyl­propane-1,3-diol

The title compound, C(11)H(14)ClNO(3), was prepared by the condensation of equimolar quanti­ties of 5-chloro­salicyl­aldehyde and 2-amino-2-methyl­propane-1,3-diol in methanol. In the crystal, it exists in the zwitterionic form, with nominal proton transfer from the phenol group to the imine N atom....

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Detalles Bibliográficos
Autores principales: Wang, Dong-Yue, Liu, Min, Ma, Jing-Jun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274988/
https://www.ncbi.nlm.nih.gov/pubmed/22346933
http://dx.doi.org/10.1107/S1600536811055784
Descripción
Sumario:The title compound, C(11)H(14)ClNO(3), was prepared by the condensation of equimolar quanti­ties of 5-chloro­salicyl­aldehyde and 2-amino-2-methyl­propane-1,3-diol in methanol. In the crystal, it exists in the zwitterionic form, with nominal proton transfer from the phenol group to the imine N atom. This results in the formation of an intra­molecular N—H⋯O hydrogen bond, which generates an S(6) ring. Inter­molecular O—H⋯O hydrogen bonds arise from the hy­droxy groups, forming (001) sheets.