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1,1′-[(2-Phenyl-2,3-dihydro-1H-benzimidazole-1,3-diyl)bis(methylene)]bis(1H-benzotriazole)
The imidazole ring in the title compound, C(27)H(22)N(8), adopts a slight envelope conformation with the C atom carrying the phenyl ring being the flap atom. The phenyl ring is almost perpendicular to the mean plane of the imidazole ring [dihedral angle = 88.90 (7)°]. The (1H-benzotriazol-1-yl)methy...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2012
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274994/ https://www.ncbi.nlm.nih.gov/pubmed/22346939 http://dx.doi.org/10.1107/S1600536811055486 |
| _version_ | 1782223151405465600 |
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| author | Rivera, Augusto Osorio, Hector Jairo Ríos-Motta, Jaime Fejfarová, Karla Dušek, Michal |
| author_facet | Rivera, Augusto Osorio, Hector Jairo Ríos-Motta, Jaime Fejfarová, Karla Dušek, Michal |
| author_sort | Rivera, Augusto |
| collection | PubMed |
| description | The imidazole ring in the title compound, C(27)H(22)N(8), adopts a slight envelope conformation with the C atom carrying the phenyl ring being the flap atom. The phenyl ring is almost perpendicular to the mean plane of the imidazole ring [dihedral angle = 88.90 (7)°]. The (1H-benzotriazol-1-yl)methyl groups bound to the imidazole ring are positioned on the same side of the imidazole ring. The dihedral angle between these benzotriazolyl rings is 17.71 (5)°. The crystal packing is stabilized by a C—H⋯π interaction, which connects the molecules into zigzag chains running along the b axis. |
| format | Online Article Text |
| id | pubmed-3274994 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2012 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-32749942012-02-15 1,1′-[(2-Phenyl-2,3-dihydro-1H-benzimidazole-1,3-diyl)bis(methylene)]bis(1H-benzotriazole) Rivera, Augusto Osorio, Hector Jairo Ríos-Motta, Jaime Fejfarová, Karla Dušek, Michal Acta Crystallogr Sect E Struct Rep Online Organic Papers The imidazole ring in the title compound, C(27)H(22)N(8), adopts a slight envelope conformation with the C atom carrying the phenyl ring being the flap atom. The phenyl ring is almost perpendicular to the mean plane of the imidazole ring [dihedral angle = 88.90 (7)°]. The (1H-benzotriazol-1-yl)methyl groups bound to the imidazole ring are positioned on the same side of the imidazole ring. The dihedral angle between these benzotriazolyl rings is 17.71 (5)°. The crystal packing is stabilized by a C—H⋯π interaction, which connects the molecules into zigzag chains running along the b axis. International Union of Crystallography 2012-01-07 /pmc/articles/PMC3274994/ /pubmed/22346939 http://dx.doi.org/10.1107/S1600536811055486 Text en © Rivera et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Organic Papers Rivera, Augusto Osorio, Hector Jairo Ríos-Motta, Jaime Fejfarová, Karla Dušek, Michal 1,1′-[(2-Phenyl-2,3-dihydro-1H-benzimidazole-1,3-diyl)bis(methylene)]bis(1H-benzotriazole) |
| title | 1,1′-[(2-Phenyl-2,3-dihydro-1H-benzimidazole-1,3-diyl)bis(methylene)]bis(1H-benzotriazole) |
| title_full | 1,1′-[(2-Phenyl-2,3-dihydro-1H-benzimidazole-1,3-diyl)bis(methylene)]bis(1H-benzotriazole) |
| title_fullStr | 1,1′-[(2-Phenyl-2,3-dihydro-1H-benzimidazole-1,3-diyl)bis(methylene)]bis(1H-benzotriazole) |
| title_full_unstemmed | 1,1′-[(2-Phenyl-2,3-dihydro-1H-benzimidazole-1,3-diyl)bis(methylene)]bis(1H-benzotriazole) |
| title_short | 1,1′-[(2-Phenyl-2,3-dihydro-1H-benzimidazole-1,3-diyl)bis(methylene)]bis(1H-benzotriazole) |
| title_sort | 1,1′-[(2-phenyl-2,3-dihydro-1h-benzimidazole-1,3-diyl)bis(methylene)]bis(1h-benzotriazole) |
| topic | Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274994/ https://www.ncbi.nlm.nih.gov/pubmed/22346939 http://dx.doi.org/10.1107/S1600536811055486 |
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