2-[(2,4,4,6,6-Penta­chloro-1,3,5,2λ(5),4λ(5),6λ(5)-triaza­triphosphinin-2-yl)aza­nid­yl]pyridinium

The title compound, C(5)H(5)Cl(5)N(5)P(3), crystallizes as a zwitterion in which the pyridine N atom is protonated. An S(6) ring motif is formed via an intra­molecular C—H⋯N hydrogen bond. The triaza­triphosphinine ring adopts an envelope conformation, with one N atom displaced by 0.145 (1) Å from t...

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Autores principales: Ahmed, Safaa A., Haque, Rosenani A., Zetty, Zulikha H., Fun, Hoong-Kun, Loh, Wan-Sin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274999/
https://www.ncbi.nlm.nih.gov/pubmed/22346944
http://dx.doi.org/10.1107/S160053681200013X
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author Ahmed, Safaa A.
Haque, Rosenani A.
Zetty, Zulikha H.
Fun, Hoong-Kun
Loh, Wan-Sin
author_facet Ahmed, Safaa A.
Haque, Rosenani A.
Zetty, Zulikha H.
Fun, Hoong-Kun
Loh, Wan-Sin
author_sort Ahmed, Safaa A.
collection PubMed
description The title compound, C(5)H(5)Cl(5)N(5)P(3), crystallizes as a zwitterion in which the pyridine N atom is protonated. An S(6) ring motif is formed via an intra­molecular C—H⋯N hydrogen bond. The triaza­triphosphinine ring adopts an envelope conformation, with one N atom displaced by 0.145 (1) Å from the other atoms. In the crystal, N—H⋯N and C—H⋯N hydrogen bonds link the mol­ecules into centrosymmetric dimers containing one R (2) (2)(7) ring motif and two R (2) (2)(8) ring motifs.
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spelling pubmed-32749992012-02-15 2-[(2,4,4,6,6-Penta­chloro-1,3,5,2λ(5),4λ(5),6λ(5)-triaza­triphosphinin-2-yl)aza­nid­yl]pyridinium Ahmed, Safaa A. Haque, Rosenani A. Zetty, Zulikha H. Fun, Hoong-Kun Loh, Wan-Sin Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(5)H(5)Cl(5)N(5)P(3), crystallizes as a zwitterion in which the pyridine N atom is protonated. An S(6) ring motif is formed via an intra­molecular C—H⋯N hydrogen bond. The triaza­triphosphinine ring adopts an envelope conformation, with one N atom displaced by 0.145 (1) Å from the other atoms. In the crystal, N—H⋯N and C—H⋯N hydrogen bonds link the mol­ecules into centrosymmetric dimers containing one R (2) (2)(7) ring motif and two R (2) (2)(8) ring motifs. International Union of Crystallography 2012-01-07 /pmc/articles/PMC3274999/ /pubmed/22346944 http://dx.doi.org/10.1107/S160053681200013X Text en © Ahmed et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Ahmed, Safaa A.
Haque, Rosenani A.
Zetty, Zulikha H.
Fun, Hoong-Kun
Loh, Wan-Sin
2-[(2,4,4,6,6-Penta­chloro-1,3,5,2λ(5),4λ(5),6λ(5)-triaza­triphosphinin-2-yl)aza­nid­yl]pyridinium
title 2-[(2,4,4,6,6-Penta­chloro-1,3,5,2λ(5),4λ(5),6λ(5)-triaza­triphosphinin-2-yl)aza­nid­yl]pyridinium
title_full 2-[(2,4,4,6,6-Penta­chloro-1,3,5,2λ(5),4λ(5),6λ(5)-triaza­triphosphinin-2-yl)aza­nid­yl]pyridinium
title_fullStr 2-[(2,4,4,6,6-Penta­chloro-1,3,5,2λ(5),4λ(5),6λ(5)-triaza­triphosphinin-2-yl)aza­nid­yl]pyridinium
title_full_unstemmed 2-[(2,4,4,6,6-Penta­chloro-1,3,5,2λ(5),4λ(5),6λ(5)-triaza­triphosphinin-2-yl)aza­nid­yl]pyridinium
title_short 2-[(2,4,4,6,6-Penta­chloro-1,3,5,2λ(5),4λ(5),6λ(5)-triaza­triphosphinin-2-yl)aza­nid­yl]pyridinium
title_sort 2-[(2,4,4,6,6-penta­chloro-1,3,5,2λ(5),4λ(5),6λ(5)-triaza­triphosphinin-2-yl)aza­nid­yl]pyridinium
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274999/
https://www.ncbi.nlm.nih.gov/pubmed/22346944
http://dx.doi.org/10.1107/S160053681200013X
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