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2-{(E)-[(2Z)-(3-Chloro-1-methyl-2,2-dioxo-3,4-dihydro-1H-2,1-benzothiazin-4-ylidene)hydrazinylidene]methyl}phenol
In the title compound, C(16)H(14)ClN(3)O(3)S, the thiazine ring adopts a sofa (half-chair) conformation, with an r.m.s. deviation from the mean plane of 0.23 Å. The S atom and S-bonded C atom exhibit the maximum deviations from the thiazine mean plane [−0.3976 (12) and 0.3179 (14) Å, respectively]...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3275000/ https://www.ncbi.nlm.nih.gov/pubmed/22346945 http://dx.doi.org/10.1107/S1600536811055978 |
Sumario: | In the title compound, C(16)H(14)ClN(3)O(3)S, the thiazine ring adopts a sofa (half-chair) conformation, with an r.m.s. deviation from the mean plane of 0.23 Å. The S atom and S-bonded C atom exhibit the maximum deviations from the thiazine mean plane [−0.3976 (12) and 0.3179 (14) Å, respectively]. The conformations around the double bonds in the R (2)C=N—N=CHR unit are Z and E. An intramolecular O—H⋯N hydrogen bond with the hydroxy group as donor generates an S(6) ring motif. In the crystal, pairs of weak C—H⋯O interactions connect the molecules, forming inversion dimers. |
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